Benzyl bromoacetate

Modify Date: 2025-08-20 17:24:08

Benzyl bromoacetate Structure
Benzyl bromoacetate structure
Common Name Benzyl bromoacetate
CAS Number 5437-45-6 Molecular Weight 229.071
Density 1.5±0.1 g/cm3 Boiling Point 287.8±0.0 °C at 760 mmHg
Molecular Formula C9H9BrO2 Melting Point N/A
MSDS Chinese USA Flash Point 116.5±20.4 °C
Symbol GHS07
GHS07
Signal Word Warning

 Use of Benzyl bromoacetate


 

 Names

Name Benzyl 2-bromoacetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 287.8±0.0 °C at 760 mmHg
Molecular Formula C9H9BrO2
Molecular Weight 229.071
Flash Point 116.5±20.4 °C
Exact Mass 227.978592
PSA 26.30000
LogP 2.66
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.556

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AF5957215
CHEMICAL NAME :
Acetic acid, bromo-, benzyl ester
CAS REGISTRY NUMBER :
5437-45-6
BEILSTEIN REFERENCE NO. :
0973658
LAST UPDATED :
199712
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C9-H9-Br-O2

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR 2810
WGK Germany 3
RTECS AF5957215
Hazard Class 6.1
HS Code 29159080

 Synthetic Route

~80%

Benzyl bromoacetate Structure

Benzyl bromoacetate

CAS#:5437-45-6

Literature: Funabiki, Kazumasa; Komeda, Takuya; Sakaida, Yuta; Kubota, Yasuhiro; Matsui, Masaki Journal of Molecular Catalysis A: Chemical, 2013 , vol. 367, p. 116 - 120

~99%

Benzyl bromoacetate Structure

Benzyl bromoacetate

CAS#:5437-45-6

Literature: Sumitomo Chemical Company, Limited; National University Corporation Tottori University Patent: EP2345651 A1, 2011 ; Location in patent: Page/Page column 11 ;

~96%

Benzyl bromoacetate Structure

Benzyl bromoacetate

CAS#:5437-45-6

Literature: Ideue, Eiji; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru Organic Syntheses, 2012 , vol. 89, p. 501 - 509

~86%

Benzyl bromoacetate Structure

Benzyl bromoacetate

CAS#:5437-45-6

Literature: Zeng, Tieqiang; Song, Gonghua; Li, Chao-Jun Chemical Communications, 2009 , # 41 p. 6249 - 6251

~%

Benzyl bromoacetate Structure

Benzyl bromoacetate

CAS#:5437-45-6

Literature: US4596791 A1, ; US 4596791 A

~%

Benzyl bromoacetate Structure

Benzyl bromoacetate

CAS#:5437-45-6

Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1435 - 1440

~%

Benzyl bromoacetate Structure

Benzyl bromoacetate

CAS#:5437-45-6

Literature: Journal of the Chemical Society, , p. 1521,1523

~%

Benzyl bromoacetate Structure

Benzyl bromoacetate

CAS#:5437-45-6

Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 1435 - 1440

~%

Benzyl bromoacetate Structure

Benzyl bromoacetate

CAS#:5437-45-6

Literature: Synthetic Communications, , vol. 32, # 5 p. 721 - 728

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

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 Synonyms

benzyl 2-bromo-acetate
Bromoacetic acid benzyl ester
phenylmethyl 2-bromoacetate
Merbac 35
EINECS 226-611-4
Acetic acid,bromo-,benzyl ester
phenylmethyl bromoacetate
Benzyl bromoacetate
Acetic acid,bromo-,phenylmethyl ester
2-Bromoacetic Acid Phenylmethyl Ester
MFCD00000190
Acetic acid, 2-bromo-, phenylmethyl ester
Caswell No. 082A
bromoacetic acid. phenylmethyl ester
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