Methyl 4-methoxysalicylate

Names

[ CAS No. ]:
5446-02-6

[ Name ]:
Methyl 4-methoxysalicylate

[Synonym ]:
methyl 2-hydroxy-4-methoxybenzoate
MFCD00008424
EINECS 226-657-5

Chemical & Physical Properties

[ Density]:
1.216g/cm3

[ Boiling Point ]:
134°C 7mm

[ Melting Point ]:
50-53 °C(lit.)

[ Molecular Formula ]:
C₉H₁₀O₄

[ Molecular Weight ]:
182.17300

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
182.05800

[ PSA ]:
55.76000

[ LogP ]:
1.18740

[ Index of Refraction ]:
1.534

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Methanol
4-Methoxysalicylic acid
2,4-Dihydroxybenzoic acid
methyl iodide
METHYL 2,4-DIMETHOXYBENZOATE
Dimethyl sulfate
methyl 2-(methoxycarbonyl)-5-methoxyphenyl phosphate
diazomethane

DownStream

2-Hydroxy-4-methoxybenzonitrile
3-bromo-2-hydroxy-5-methoxybenzaldehyde
2-Hydroxy-4-methoxybenzohydrazide
4-HYDROXY-7-METHOXY-3-PHENYLCOUMARIN 9&
4-Methoxy Salicylamide
Methyl 2-(allyloxy)-4-methoxybenzoate
methyl 4-methoxy-2-(2-methoxy-2-oxoethoxy)benzoate
2-(Benzyloxy)-4-methoxybenzoic acid
3-Methoxy-4-nitrophenol
4-Methoxysalicylic acid

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

The first asymmetric total synthesis of (+)-coriandrone A and B.

Org. Biomol. Chem. 11(39) , 6686-90, (2013)

The first enantioselective total synthesis of (+)-coriandrone A and B, two bioactive natural products, has been achieved in 10 steps and 11 steps starting from commercially available methyl 2-hydroxy-...

methyl 4-(hydroxymethyl)-1H-pyrrole-2-carboxylate
methyl 4,5-dipropyl-1H-pyrrole-2-carboxylate
methyl 4-hexyl-5-thiophen-2-ylthiophene-2-carboxylate
methyl 4-methyl-3-((4-(pyridin-3-yl)pyrimidin-2-yl)amino)benzoate
methyl 4-(4,6,11-trioxa-1-aza-5-silabicyclo[3.3.3]undecan-5-yloxy)benzoate
methyl 4-formyl-5-phenyl-5-thiophen-2-ylpenta-2,4-dienoate
2-(Aminomethyl)-5-ethynylphenol hydrochloride
(Z)-2-(3-(2-(1-(tert-Butoxycarbonyl)piperidin-4-yl)ethylidene)-2-oxopiperidin-1-yl)acetic acid
Dimethyl 2-(1-(tert-butoxycarbonyl)-1H-indol-5-yl)bicyclo[1.1.1]pentane-1,3-dicarboxylate
Rel-(1R,2R)-2-((tert-butyldiphenylsilyl)oxy)-5-methylcyclopentane-1-carboxylic acid
tert-Butyl (S)-3-(oxazol-4-yl)piperazine-1-carboxylate
4-(Hydroxymethyl)-3-(pyridin-3-ylmethoxy)benzaldehyde
Methyl 6-(3-ethyl-2,6-difluorophenyl)picolinate
tert-Butyl 3-(1-((oxazol-4-ylmethyl)amino)ethyl)piperidine-1-carboxylate
rel-(2R,4R)-1-(tert-Butoxycarbonyl)-4-(difluoromethyl)-4-hydroxypiperidine-2-carboxylic acid
Methyl 2-cyclopropyl-3-(o-tolyl)propanoate

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