Methyl 4-methoxysalicylate

Modify Date: 2024-01-04 16:43:43

Methyl 4-methoxysalicylate Structure
Methyl 4-methoxysalicylate structure
Common Name Methyl 4-methoxysalicylate
CAS Number 5446-02-6 Molecular Weight 182.17300
Density 1.216g/cm3 Boiling Point 134°C 7mm
Molecular Formula C9H10O4 Melting Point 50-53 °C(lit.)
MSDS Chinese USA Flash Point >230 °F
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name Methyl 4-methoxysalicylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.216g/cm3
Boiling Point 134°C 7mm
Melting Point 50-53 °C(lit.)
Molecular Formula C9H10O4
Molecular Weight 182.17300
Flash Point >230 °F
Exact Mass 182.05800
PSA 55.76000
LogP 1.18740
Index of Refraction 1.534

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2942000000

 Synthetic Route

~83%

Methyl 4-methoxysalicylate Structure

Methyl 4-methox...

CAS#:5446-02-6

Literature: Journal of the American Chemical Society, , vol. 107, p. 256 - 257

~75%

Methyl 4-methoxysalicylate Structure

Methyl 4-methox...

CAS#:5446-02-6

Literature: Journal of Organic Chemistry, , vol. 72, # 5 p. 1803 - 1806

~94%

Methyl 4-methoxysalicylate Structure

Methyl 4-methox...

CAS#:5446-02-6

Literature: Journal of Chemical Research, , # 4 p. 222 - 227

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Methyl 4-methoxysalicylate Structure

Methyl 4-methox...

CAS#:5446-02-6

Literature: Journal of the Chemical Society, , p. 1618 Journal of the American Chemical Society, , vol. 64, p. 2986

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Methyl 4-methoxysalicylate Structure

Methyl 4-methox...

CAS#:5446-02-6

Literature: Journal of the American Chemical Society, , vol. 70, p. 2697

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Methyl 4-methoxysalicylate Structure

Methyl 4-methox...

CAS#:5446-02-6

Literature: Journal of the American Chemical Society, , vol. 131, p. 368 - 377

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Methyl 4-methoxysalicylate Structure

Methyl 4-methox...

CAS#:5446-02-6

Literature: Journal of the Indian Chemical Society, , vol. 28, p. 459,463 Journal of Organic Chemistry, , vol. 23, p. 756

~%

Methyl 4-methoxysalicylate Structure

Methyl 4-methox...

CAS#:5446-02-6

Literature: Monatshefte fuer Chemie, , vol. 24, p. 887

~86%

Methyl 4-methoxysalicylate Structure

Methyl 4-methox...

CAS#:5446-02-6

Literature: US2009/69430 A1, ; Page/Page column 14 ;

 Customs

HS Code 2918990090
Summary 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles1

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The first asymmetric total synthesis of (+)-coriandrone A and B.

Org. Biomol. Chem. 11(39) , 6686-90, (2013)

The first enantioselective total synthesis of (+)-coriandrone A and B, two bioactive natural products, has been achieved in 10 steps and 11 steps starting from commercially available methyl 2-hydroxy-...

 Synonyms

methyl 2-hydroxy-4-methoxybenzoate
MFCD00008424
EINECS 226-657-5