Tetramethylbenzidine

Suppliers

Names

[ CAS No. ]:
54827-17-7

[ Name ]:
Tetramethylbenzidine

[Synonym ]:
3355TMB
3,3,5',5'-Tetramethylbenzidine
UNII-3B3T5CB8EO
TMB/H
TMB-E
TMB/M
3,3’,5,5’-tetramethylbenzidine
EINECS 259-364-6
TMB
BM BLUE
3,3',5,5'-Tetramethyl-4,4'-biphenyldiamine
3,3',5,5'-tetramethyl-4,4'-diamino-1,1'-biphenyl
TMB QUICK
3,3',5,5'-tetramethylbenzidine
Tmbz
MFCD00007748
3,3',5,5'-Tetramethylbiphenyl-4,4'-diamine
3,5,3',5'-tetramethylbenzidine
TMB EASY
TMB-B
[1,1'-Biphenyl]-4,4'-diamine, 3,3',5,5'-tetramethyl-

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
368.6±37.0 °C at 760 mmHg

[ Melting Point ]:
168-171 °C(lit.)

[ Molecular Formula ]:
C16H20N2

[ Molecular Weight ]:
240.343

[ Flash Point ]:
210.8±26.0 °C

[ Exact Mass ]:
240.162643

[ PSA ]:
52.04000

[ LogP ]:
3.40

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.618

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable, but moisture sensitive and may be light sensitive. Incompatible with water, strong oxidizing agents.

[ Water Solubility ]:
Slightly soluble.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DV2300000
CHEMICAL NAME :
(1,1'-Biphenyl)-4,4-diamine, 3,3',5,5'-tetramethyl-
CAS REGISTRY NUMBER :
54827-17-7
LAST UPDATED :
199710
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C16-H20-N2
MOLECULAR WEIGHT :
240.38
WISWESSER LINE NOTATION :
ZR B1 F1 DR DZ C1 E1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
135 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
>316 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
Micronucleus test

MUTATION DATA

TYPE OF TEST :
Mutation in mammalian somatic cells
TEST SYSTEM :
Rodent - mouse Lymphocyte
DOSE/DURATION :
30700 ug/L
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 12(Suppl 13),37,1988

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37

[ RIDADR ]:
UN 2796 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
DV2300000

[ Hazard Class ]:
8.0

[ HS Code ]:
29215990

Synthetic Route

Precursor & DownStream

Precursor

  • 4-CHLORO-2,6-DIMETHYLANILINE
  • 4-bromo-2,6-xylidine
  • 2,6-dimethyl phenyl hydrazine

DownStream

  • 2-bromo-5-(4-bromo-3,5-dimethylphenyl)-1,3-dimethylbenzene

Customs

[ HS Code ]: 2921590090

[ Summary ]:
2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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Related Compounds

  • Tetramethylbenzidine
  • 3,3,5',5'-Tetramethylbenzidine
  • 2,2',6,6'-tetramethylbenzidine
  • N,N,N',N'-TETRAMETHYLBENZIDINE
  • Tetramethylbenzidine bis-ethiodide
  • Tetramethylbenzidine bis-iodobenzylate
  • 5-(difluoromethyl)-1H-imidazol-2-amine
  • N-Cyclopropyl-2-nitropyridin-3-amine
  • Carbamic acid, (6-amino-4-quinazolinyl)-, 1,1-dimethylethyl ester
  • 3-(Furan-2-yl)pyrazine-2-carbaldehyde
  • 2-(2-Chloro-6-fluorophenyl)butanedioic acid
  • 2-(1-Bromopropan-2-yl)-4-fluoro-1-methoxybenzene
  • 2-[[trans-4-(Bromomethyl)cyclohexyl]methoxy]tetrahydro-2H-pyran
  • 2-Amino-1-{[2,2'-bithiophene]-5-yl}ethan-1-ol
  • 2-[3-(4-Ethylphenyl)phenyl]ethan-1-amine
  • 3-(5-Chloro-2-methoxyphenyl)piperidine