L-Glutamine

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Names

[ CAS No. ]:
56-85-9

[ Name ]:
L-Glutamine

[Synonym ]:
UNII-U5JDO2770Z
EINECS 200-292-1
(2S)-2-((2S)-2-Aminopropanoylamino)-4-carbamoylbutanoic acid
ZY1&VMYVQ2VZ &&L-L Form
glutaminic acid
Gln
L-Ala-L-Gln
glutamine
L-Gln
Pentanoic acid, 2,5-diamino-5-oxo-, (S)-
L-Alanyl-L-glutamine
Levoglutamide
(S)-5-Amino-2-[(S)-2-aminopropanamido]-5-oxopentanoic acid
L-Glutamine,L-alanyl
2,5-Diamino-5-oxopentanoic acid, (S)-
(2S)-2-amino-4-carbamoylbutanoic acid
Alanyl-glutamine,Glutamine-S
MFCD00008044
Ala-Gln
L-(+)-Glutamine
2-Aminoglutaramic acid, L-
(S)-(+)-Glutamine
5-Hydroxy-5-imino-L-norvaline
N(2)-L-alanyl-L-glutamine
Glutamine-S
Alanyl-glutamine
L-Norvaline, 5-hydroxy-5-imino-
L-Glutamic Acid g-Amide
L-Glutamic acid γ-amide
N-L-alanyl-L-glutamine
L-Glutamine, N2-L-alanyl-
L-Glutamine
l-alanyl-l-glutamin
l-(+)-glutamic acid-5-amide
L-Glutamic acid 5-amide
H-Ala-Gln-OH
GLUTAMINE, L-
(2S)-5-Amino-2-{[(2S)-2-aminopropanoyl]amino}-5-oxopentanoic acid
L-Glutamine, L-alanyl-
S(+)-Glutamic acid 5-amide
H-Gln-OH

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
353.5±52.0 °C at 760 mmHg

[ Melting Point ]:
185ºC

[ Molecular Formula ]:
C5H10N2O3

[ Molecular Weight ]:
146.145

[ Flash Point ]:
167.6±30.7 °C

[ Exact Mass ]:
146.069138

[ PSA ]:
106.41000

[ LogP ]:
-1.28

[ Vapour Pressure ]:
0.0±1.8 mmHg at 25°C

[ Index of Refraction ]:
1.564

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MA2275100
CHEMICAL NAME :
Glutamine, L-
CAS REGISTRY NUMBER :
56-85-9
BEILSTEIN REFERENCE NO. :
1723797
LAST UPDATED :
199706
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C5-H10-N2-O3
MOLECULAR WEIGHT :
146.17
WISWESSER LINE NOTATION :
ZV2YZVQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
27 mg/kg/1W-I
TOXIC EFFECTS :
Behavioral - euphoria
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
21700 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
260 mg/kg/30D-I
TOXIC EFFECTS :
Behavioral - food intake (animal) Blood - changes in spleen Related to Chronic Data - death

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
10 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 372,75,1996 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4814 No. of Facilities: 841 (estimated) No. of Industries: 4 No. of Occupations: 14 No. of Employees: 8491 (estimated) No. of Female Employees: 5700 (estimated)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
MA2275100

[ HS Code ]:
2932999099

Synthetic Route

Precursor & DownStream

Precursor

  • Fmoc-Gln-OH
  • L-glutamic acid
  • mercaptoethanol
  • Boc-L-glutamic acid 1-benzyl ester
  • Aceglutamide
  • L-Glutamine

DownStream

  • dansyl-l-glutamine
  • Thalidomide
  • 5-Oxopyrrolidine-2-carboxylic acid
  • 2-Ketoglutaric acid
  • 2-Keto-glutaramic acid
  • L-Alanyl-L-Glutamine
  • L-Theanine
  • L-glutamic acid
  • monosodium glutamate
  • 2H-Isoindole-2-aceticacid, a-(3-amino-3-oxopropyl)-1,3-dihydro-1,3-dioxo-,(aS)-

Customs

[ HS Code ]: 2924199090

[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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Related Compounds

  • L-glutamine
  • L-Glutamine
  • L-Glutamine-d5
  • L-Glutamine-N-N
  • L-Glutamine-5-C
  • Boc-L-Glutamine
  • Tert-butyl 3-({[(tert-butoxy)carbonyl](methyl)amino}methyl)-3-hydroxypiperidine-1-carboxylate
  • benzyl N-(1-ethyl-1H-1,3-benzodiazol-2-yl)-N-(3-hydroxypropyl)carbamate
  • 5-Amino-1-[(1,2-thiazol-5-yl)methyl]-1,2-dihydropyridin-2-one
  • 4-bromo-1-(3,3-dimethylpentyl)-1H-pyrazol-3-amine
  • 4-chloro-1-[(2-chlorothiophen-3-yl)methyl]-1H-pyrazol-3-amine
  • 1-[(5,5-dimethyloxolan-2-yl)methyl]-5-methyl-1H-pyrazol-3-amine
  • benzyl N-[3-(5,6-dimethyl-1H-1,3-benzodiazol-1-yl)-2-hydroxypropyl]carbamate
  • 6-({[(Benzyloxy)carbonyl]amino}methyl)-3,4-dimethylcyclohex-3-ene-1-sulfonic acid
  • benzyl N-benzyl-N-[1-(hydroxymethyl)cyclohexyl]carbamate
  • 5-methyl-1-[2-(1-methyl-1H-pyrazol-5-yl)ethyl]-1H-pyrazol-3-amine
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