1-Bromo-2-nitrobenzene

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Names

[ CAS No. ]:
577-19-5

[ Name ]:
1-Bromo-2-nitrobenzene

[Synonym ]:
o-Nitrophenyl bromide
ortho-nitrobromobenzene
Benzene,1-bromo-2-nitro
2-bromo-1-nitrobenzene
1-Bromo-2-nitrobenzene
bromo-nitrobenzene
2-Bromonitrobenzene
Benzene, 1-bromo-2-nitro-
WNR BE
o-Nitrobromobenzene
MFCD00007045
o-Bromonitrobenzene
EINECS 209-409-0
1-bromonitrobenzene
2-Nitrobromobenzene

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
261.0±0.0 °C at 760 mmHg

[ Melting Point ]:
40-42 °C(lit.)

[ Molecular Formula ]:
C6H4BrNO2

[ Molecular Weight ]:
202.005

[ Flash Point ]:
87.8±19.8 °C

[ Exact Mass ]:
200.942535

[ PSA ]:
45.82000

[ LogP ]:
2.52

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.606

[ Stability ]:
Stable. Combustible. Incompatible with strong bases, strong oxidizing agents.

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CY9040450
CHEMICAL NAME :
Benzene, 1-bromo-2-nitro-
CAS REGISTRY NUMBER :
577-19-5
LAST UPDATED :
199710
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C6-H4-Br-N-O2
MOLECULAR WEIGHT :
202.02

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
250 ug/plate
REFERENCE :
SAIGBL Sangyo Igaku. Japanese Journal of Industrial Health. (Nippon Sangyo Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160, Japan) V.1- 1959- Volume(issue)/page/year: 29,34,1987

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S36/37-S36/37/39-S26-S22

[ RIDADR ]:
UN 3459 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
CY9040450

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29049085

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Nitroaniline
  • 2-Bromoaniline
  • Bromobenzene
  • 2-Nitrobenzoic acid
  • 1-Iodo-2-nitrobenzene
  • 2-Bromophenylboronic acid
  • 3-Bromo-4-nitrobenzoic acid
  • nitrobenzene
  • (2-nitrophenyl) trifluoromethanesulfonate
  • 2-nitroaniline hydrochloride

DownStream

  • Diethyl (2-nitrophenyl)malonate
  • Ethanone,1-(9H-carbazol-9-yl)-
  • 3-Bromo-4-nitroaniline
  • METHYL 2-NITROBENZOATE
  • 2-FURAN-2-YL-PHENYLAMINE
  • 4'-METHOXY-BIPHENYL-2-YLAMINE
  • Benzenamine,N-(4-methoxyphenyl)-2-nitro-
  • 2-Bromo-6-nitrophenol
  • 2-Bromo-4-nitrophenol
  • 3-Bromo-4-nitrophenol

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Organo-palladium(II) complexes bearing unsymmetrical N,N,N-pincer ligands: synthesis, structures and oxidatively induced coupling reactions.

Dalton Trans. 44(16) , 7230-41, (2015)

The 2-(2′-aniline)-6-imine-pyridines, 2-(C6H4-2′-NH2)-6-(CMe=NAr)C5H3N (Ar = 4-i-PrC6H4 (HL1a), 2,6-i-Pr2C6H3 (HL1b)), have been synthesised via sequential Stille cross-coupling, deprotection and cond...

Synthesis of quinolines, 2-quinolones, phenanthridines, and 6(5h)-phenanthridinones via palladium[0]-mediated Ullmann cross-coupling of 1-bromo-2-nitroarenes with beta-halo-enals, -enones, or -esters.

Org. Lett. 6(16) , 2741-4, (2004)

Palladium[0]-mediated Ullmann cross-coupling of 1-bromo-2-nitrobenzene (1 R = H) and its derivatives with a range of beta-halo-enals, -enones, or -esters readily affords the corresponding beta-aryl de...

New protocols for the synthesis of 3, 4-annulated and 4-substituted quinolines from ß-bromo-a, ß-unsaturated aldehydes and 1-bromo-2-nitrobenzene or 2-bromoacetanilide. Some S, et al.

Tetrahedron Lett. 48(20) , 3609-12, (2007)


More Articles

Related Compounds

  • 1-Bromo-2-nitrobenzene-d4
  • 1-Bromo-2-(bromomethyl)-3-nitrobenzene
  • 1-Bromo-2-methoxy-3-nitrobenzene
  • 1-Bromo-2-(difluoromethoxy)-4-nitrobenzene
  • 1-bromo-2-methylsulfanyl-4-nitrobenzene
  • 1-Bromo-2-methyl-4-nitrobenzene
  • 3-(4-chlorophenyl)-N-[2-(1H-indol-3-yl)ethyl]-[1,2,3]triazolo[1,5-a]quinazolin-5-amine
  • 3-(4-Chlorophenyl)-N-[2-(3,4-diethoxyphenyl)ethyl]-[1,2,3]triazolo[1,5-A]quinazolin-5-amine
  • 3-(4-methylphenyl)-N-[(oxolan-2-yl)methyl]-[1,2,3]triazolo[1,5-a]quinazolin-5-amine
  • N-cycloheptyl-3-(4-methylphenyl)-[1,2,3]triazolo[1,5-a]quinazolin-5-amine
  • N-[(2-chlorophenyl)methyl]-3-(3-methylphenyl)-[1,2,3]triazolo[1,5-a]quinazolin-5-amine
  • N-[(4-fluorophenyl)methyl]-3-[3-(trifluoromethyl)phenyl]-[1,2,3]triazolo[1,5-a]quinazolin-5-amine
  • 5-(Methylsulfonyl)-2-phenyl-1H-benzo[d]imidazole
  • N-[(3-methoxyphenyl)methyl]-3-[3-(trifluoromethyl)phenyl]-[1,2,3]triazolo[1,5-a]quinazolin-5-amine
  • 4-Methyl-1-{3-[3-(trifluoromethyl)phenyl]-[1,2,3]triazolo[1,5-a]quinazolin-5-yl}piperidine
  • 7-Chloro-N-(2-phenylethyl)-3-[3-(trifluoromethyl)phenyl]-[1,2,3]triazolo[1,5-A]quinazolin-5-amine
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