1-Bromo-2-nitrobenzene
Suppliers
Names
[ CAS No. ]:
577-19-5
[ Name ]:
1-Bromo-2-nitrobenzene
[Synonym ]:
o-Nitrophenyl bromide
ortho-nitrobromobenzene
Benzene,1-bromo-2-nitro
2-bromo-1-nitrobenzene
1-Bromo-2-nitrobenzene
bromo-nitrobenzene
2-Bromonitrobenzene
Benzene, 1-bromo-2-nitro-
WNR BE
o-Nitrobromobenzene
MFCD00007045
o-Bromonitrobenzene
EINECS 209-409-0
1-bromonitrobenzene
2-Nitrobromobenzene
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
261.0±0.0 °C at 760 mmHg
[ Melting Point ]:
40-42 °C(lit.)
[ Molecular Formula ]:
C6H4BrNO2
[ Molecular Weight ]:
202.005
[ Flash Point ]:
87.8±19.8 °C
[ Exact Mass ]:
200.942535
[ PSA ]:
45.82000
[ LogP ]:
2.52
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.606
[ Stability ]:
Stable. Combustible. Incompatible with strong bases, strong oxidizing agents.
[ Water Solubility ]:
insoluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CY9040450
- CHEMICAL NAME :
- Benzene, 1-bromo-2-nitro-
- CAS REGISTRY NUMBER :
- 577-19-5
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 4
- MOLECULAR FORMULA :
- C6-H4-Br-N-O2
- MOLECULAR WEIGHT :
- 202.02
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- DOSE/DURATION :
- 250 ug/plate
- REFERENCE :
- SAIGBL Sangyo Igaku. Japanese Journal of Industrial Health. (Nippon Sangyo Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160, Japan) V.1- 1959- Volume(issue)/page/year: 29,34,1987
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H312-H332
[ Precautionary Statements ]:
P280
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R20/21/22;R36/37/38
[ Safety Phrases ]:
S36/37-S36/37/39-S26-S22
[ RIDADR ]:
UN 3459 6.1/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
CY9040450
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
[ HS Code ]:
29049085
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2904909090
[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Dalton Trans. 44(16) , 7230-41, (2015)
The 2-(2′-aniline)-6-imine-pyridines, 2-(C6H4-2′-NH2)-6-(CMe=NAr)C5H3N (Ar = 4-i-PrC6H4 (HL1a), 2,6-i-Pr2C6H3 (HL1b)), have been synthesised via sequential Stille cross-coupling, deprotection and cond...
Org. Lett. 6(16) , 2741-4, (2004)
Palladium[0]-mediated Ullmann cross-coupling of 1-bromo-2-nitrobenzene (1 R = H) and its derivatives with a range of beta-halo-enals, -enones, or -esters readily affords the corresponding beta-aryl de...
New protocols for the synthesis of 3, 4-annulated and 4-substituted quinolines from ß-bromo-a, ß-unsaturated aldehydes and 1-bromo-2-nitrobenzene or 2-bromoacetanilide. Some S, et al.Tetrahedron Lett. 48(20) , 3609-12, (2007)