L-Tyrosine

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Names

[ CAS No. ]:
60-18-4

[ Name ]:
L-Tyrosine

[Synonym ]:
L-tyrosine zwitterion
hydrogen L-tyrosinate
MEVINOLIN
LOVALIP
a-Amino-p-hydroxyhydrocinnamic Acid
L-Phenylalanine, 4-hydroxy-
LOVASTIN
MEVACOR
H-Tyr-OH
Tyrosine
MFCD00002606
L-Tyr
Rovacor
Tyr
(S)-(-)-Tyrosine
Sivlor
L-Tyrosine
(S)-a-Amino-4-hydroxybenzenepropanoic acid
Tyrosine, L-
b-(p-Hydroxyphenyl)alanine
mevlor
Benzenepropanoic acid, α-amino-4-hydroxy-, (S)-
Tyrosinum [Latin]
(S)-a-amino-4-hydroxy-Benzenepropanoic acid
(S)-tyrosine
(S)-α-amino-4-hydroxy-Benzenepropanoic acid
EINECS 200-460-4
msd803
Paschol

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
385.2±32.0 °C at 760 mmHg

[ Melting Point ]:
>300 °C (dec.)(lit.)

[ Molecular Formula ]:
C9H11NO3

[ Molecular Weight ]:
181.189

[ Flash Point ]:
186.7±25.1 °C

[ Exact Mass ]:
181.073898

[ PSA ]:
83.55000

[ LogP ]:
0.38

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.614

[ Water Solubility ]:
0.45 g/L (25 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YP2275600
CHEMICAL NAME :
Tyrosine, L-
CAS REGISTRY NUMBER :
60-18-4
LAST UPDATED :
199709
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C9-H11-N-O3
MOLECULAR WEIGHT :
181.21
WISWESSER LINE NOTATION :
QVYZ1R DQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>1450 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
42 gm/kg/2W-C
TOXIC EFFECTS :
Behavioral - food intake (animal) Biochemical - Metabolism (Intermediary) - amino acids (including renal excretion) Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
20750 mg/kg
SEX/DURATION :
female 15-19 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - other effects to embryo
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
5 gm/kg
SEX/DURATION :
female 11-20 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Newborn - behavioral
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
3500 mg/kg
SEX/DURATION :
female 15-21 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - Central Nervous System
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
DOSE :
150 mg/kg
SEX/DURATION :
female 3 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Maternal Effects - ovaries, fallopian tubes
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
3 gm/kg
SEX/DURATION :
female 29-31 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Newborn - biochemical and metabolic

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
10 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 372,75,1996 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81869 No. of Facilities: 133 (estimated) No. of Industries: 2 No. of Occupations: 4 No. of Employees: 1421 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81869 No. of Facilities: 275 (estimated) No. of Industries: 3 No. of Occupations: 12 No. of Employees: 14731 (estimated) No. of Female Employees: 12371 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
YP2275600

[ HS Code ]:
29225000

Synthetic Route

Precursor & DownStream

Precursor

  • 2-benzamido-3-(4-hydroxyphenyl)prop-2-enoic acid
  • Boc-Tyr-OH
  • D,L-TyrO-iPr
  • Nα-(allyloxycarbonyl)tyrosine O-allyl ether
  • 4-Hydroxyphenylpyruvic acid

DownStream

  • 3-Acetyl-N-benzyloxycarbonyl-L-tyrosine Methyl Ester
  • Dimethylamine
  • methylamine
  • Trimethylamine
  • 3-Acetyl-N-benzyloxycarbonyl-4-O-benzyl-L-tyrosine Methyl Ester
  • 3,5-dibromotyrosine trifluoroacetamide methyl ester
  • H-Tyr-OMe.HCl
  • N-Methyltyramine
  • Indole
  • 1H-Indole-5,6-diol

Customs

[ HS Code ]: 2922509090

[ Summary ]:
2922509090. other amino-alcohol-phenols, amino-acid-phenols and other amino-compounds with oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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Related Compounds

  • L-Tyrosine
  • L-Tyrosine
  • L-Tyrosine-C
  • L-Tyrosine-d2
  • L-Tyrosine-d3
  • L-Tyrosine-d5
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine