2-Aminoethanethiol

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Names

[ CAS No. ]:
60-23-1

[ Name ]:
2-Aminoethanethiol

[Synonym ]:
b-MEA
Ethanethiol, 2-amino-
2-Aminoethanethiol
Thioethanolamine
β-aminoethylthiol
β-mercaptoethylamine
Mercamine
MEA
mercaptoethylamine
mercaptamine
b-Aminoethylthiol
Merkamin
b-Aminoethanethiol
Mercaptamin
2-mercaptoethylamine
b-Mercaptoethylamine
MFCD00008196
cysteamine
Decarboxycysteine
β-Aminoethanethiol
EINECS 200-463-0

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
133.6±23.0 °C at 760 mmHg

[ Melting Point ]:
95°C

[ Molecular Formula ]:
C2H7NS

[ Molecular Weight ]:
77.149

[ Flash Point ]:
34.6±22.6 °C

[ Exact Mass ]:
77.029922

[ PSA ]:
64.82000

[ LogP ]:
0.03

[ Vapour Pressure ]:
8.4±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.486

[ Stability ]:
Stable, but may be air-sensitive. Incompatible with strong oxidizing agents.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KJ0175000
CHEMICAL NAME :
Ethanethiol, 2-amino-
CAS REGISTRY NUMBER :
60-23-1
LAST UPDATED :
199710
DATA ITEMS CITED :
17
MOLECULAR FORMULA :
C2-H7-N-S
MOLECULAR WEIGHT :
77.16
WISWESSER LINE NOTATION :
Z2SH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
232 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
84 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - convulsions or effect on seizure threshold Skin and Appendages - hair
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
625 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
84 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - convulsions or effect on seizure threshold Skin and Appendages - hair
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
190 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
350 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
150 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
42 gm/kg
SEX/DURATION :
female 70 day(s) pre-mating - 21 day(s) post-birth
TOXIC EFFECTS :
Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth) Reproductive - Fertility - other measures of fertility

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
100 umol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 68,351,1979

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
3259

[ WGK Germany ]:
3

[ RTECS ]:
KJ0175000

Synthetic Route

Precursor & DownStream

Precursor

  • Cysteamine Hydrochloride
  • Aziridine
  • Ethanamine,2-[(triphenylmethyl)thio]-
  • hydrogen sulfide
  • 1-thia-4-azaspiro[4.5]decane
  • Thiosulfuric acid(H2S2O3), S-(2-aminoethyl) ester
  • L-cysteine
  • Cystamine
  • Glutathione

DownStream

  • 2-(DIMETHYLAMINO)ETHANETHIOL
  • 2-phenylthiazolidine
  • Thiazolidine,2-(4-methoxyphenyl)-
  • N,S-Diacetylcysteamine
  • Aminothiazoline
  • Thiazolidine
  • 4,5-dihydro-1,3-thiazole
  • 2-pentyl-4,5-dihydro-1,3-thiazole
  • Glutathione

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Related Compounds

  • Ni(2-aminoethanethiol)2
  • N-methyl-2-aminoethanethiol
  • potassium 2-aminoethanethiol
  • S-nitroso-2-aminoethanethiol
  • S-propargyl-2-aminoethanethiol
  • 2-aminoethanethiol,hydrobromide
  • 4-phenyl-N-(pyridin-3-ylmethyl)-1,2,3-thiadiazole-5-carboxamide
  • N-(3-methoxyphenyl)cyclopropanesulfonamide
  • N,1-diisopropyl-1H-imidazol-2-amine
  • pyrrolidin-1-yl[2-(1H-pyrrol-1-yl)-5,6-dihydro-4H-cyclopenta[b]thiophen-3-yl]methanone
  • 5-(5-Bromo-2-methoxyphenyl)imidazolidine-2,4-dione
  • 3-(4-Methoxyphenyl)-1-methylpiperazine-2,5-dione
  • 1-(3,4-Dimethylphenyl)-4-isocyanato-2-pyrrolidinone
  • 2,6-dichloro-N-[3-([1,2,4]triazolo[4,3-a]pyridin-3-yl)propyl]pyridine-3-carboxamide
  • [1-(Furan-2-yl)cyclohexyl]methanamine
  • 1-(1H-indol-1-ylacetyl)piperidine-3-carboxylic acid
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