Methyl 2-methoxybenzoate

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Names

[ CAS No. ]:
606-45-1

[ Name ]:
Methyl 2-methoxybenzoate

[Synonym ]:
Methyol o-methoxybenzoate
Methyl o-anisate
dimethyl salicylate
methyl methoxybenzoate
Methyl o-methoxybenzoate
methoxy-benzoic acid methyl ester
2-Methoxybenzoic Acid Methyl Ester
BENZOIC ACID,2-METHOXY-,METHYL ESTER
methyl monomethoxybenzoate
o-Methoxybenzoic acid methyl ester
Benzoic acid, 2-methoxy-, methyl ester
Methyl 2-methoxybenzoate
o-Anisic acid,methyl ester
EINECS 210-118-6
MFCD00008423

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
245.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C9H10O3

[ Molecular Weight ]:
166.174

[ Flash Point ]:
93.8±14.4 °C

[ Exact Mass ]:
166.062988

[ PSA ]:
35.53000

[ LogP ]:
2.04

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.503

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DH3549000
CHEMICAL NAME :
Benzoic acid, 2-methoxy-, methyl ester
CAS REGISTRY NUMBER :
606-45-1
BEILSTEIN REFERENCE NO. :
2207356
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C9-H10-O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 26,385,1988
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 26,385,1988

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
DH3549000

[ HS Code ]:
29189090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • 2-Methoxybenzoic acid
  • Dimethyl sulfate
  • Salicylic acid
  • o-Anisaldehyde
  • tert-Butyl Hydroperoxide
  • bromoanisole
  • carbon monoxide
  • o-anisoyl chloride
  • Anisole

DownStream

  • 2-METHOXY-5-NITROBENZOIC ACID
  • Methyl 2-methoxy-5-nitrobenzoate
  • 3-(2-Methoxyphenyl)-3-oxopropanenitrile
  • Ethyl 3-(2-methoxyphenyl)-3-oxopropanoate
  • Methyl cyclohexanoate
  • 1-carbomethoxy-2-methoxycyclohexane
  • 2-(2-METHOXYBENZOYL)PYRIDINE
  • 2-Cyanophenol
  • 2-Methoxybenzonitrile
  • 2-Methoxybenzoic acid

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Cross dehydrogenative arylation (CDA) of a benzylic C-H bond with arenes by iron catalysis.

Angew. Chem. Int. Ed. Engl. 48(21) , 3817-20, (2009)

Hooking up: FeCl(2) catalyzes the efficient cross dehydrogenative arylation of substrates having benzylic C-H bonds (see scheme). High regioselectivity was observed during the cross-coupling between c...

Synthesis of (+/-)-vibralactone.

Org. Lett. 10(7) , 1401-4, (2008)

Reductive alkylation of methyl 2-methoxybenzoate with prenyl bromide and hydrolysis afforded methyl 6-oxo-1-prenyl-2-cyclohexenecarboxylate. Reduction of the ketone, hydrolysis, iodolactonization, ozo...


More Articles

Related Compounds

  • methyl 4-[(acetyloxy)methyl]-2-methoxybenzoate
  • methyl 5-iodo-2-methoxy-3-methylbenzoate
  • Methyl 2-ethyl-6-methoxybenzoate
  • Methyl 2-hydroxy-5-methoxybenzoate
  • Methyl 2-Amino-4-Methoxybenzoate
  • Methyl 2-bromo-6-methoxybenzoate
  • 4-(2-(2-phenyl-1H-imidazol-1-yl)ethyl)-N-(3-(trifluoromethyl)phenyl)piperazine-1-carboxamide
  • 2-(4-chlorophenoxy)-N-(2-((3-cyclopropyl-1,2,4-oxadiazol-5-yl)methyl)phenyl)-2-methylpropanamide
  • N-(2-((3-cyclopropyl-1,2,4-oxadiazol-5-yl)methyl)phenyl)-2-oxoimidazolidine-1-carboxamide
  • 2-(benzo[d]oxazol-2-ylthio)-N-(2-((3-(thiophen-2-yl)-1,2,4-oxadiazol-5-yl)methyl)phenyl)acetamide
  • 1-(4-Methoxyphenethyl)-3-(2-((3-(pyrazin-2-yl)-1,2,4-oxadiazol-5-yl)methyl)phenyl)urea
  • 1-(2-((3-(Pyrazin-2-yl)-1,2,4-oxadiazol-5-yl)methyl)phenyl)-3-(3-(trifluoromethyl)phenyl)urea
  • 1-(4-Fluorobenzyl)-3-(2-((3-(pyrazin-2-yl)-1,2,4-oxadiazol-5-yl)methyl)phenyl)urea
  • (3-(4-Fluorophenyl)azepan-1-yl)(5-(furan-2-yl)isoxazol-3-yl)methanone
  • 3-(3-(4-fluorophenyl)azepane-1-carbonyl)-1-methylpyridin-2(1H)-one
  • 3-(Piperazin-1-yl)-1-(2,2,2-trifluoroethyl)piperidin-2-one
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