Methyl 2-methoxybenzoate

Methyl 2-methoxybenzoate Structure
Methyl 2-methoxybenzoate structure
Common Name Methyl 2-methoxybenzoate
CAS Number 606-45-1 Molecular Weight 166.174
Density 1.1±0.1 g/cm3 Boiling Point 245.0±0.0 °C at 760 mmHg
Molecular Formula C9H10O3 Melting Point N/A
MSDS Chinese USA Flash Point 93.8±14.4 °C

Cross dehydrogenative arylation (CDA) of a benzylic C-H bond with arenes by iron catalysis.

Angew. Chem. Int. Ed. Engl. 48(21) , 3817-20, (2009)

Hooking up: FeCl(2) catalyzes the efficient cross dehydrogenative arylation of substrates having benzylic C-H bonds (see scheme). High regioselectivity was observed during the cross-coupling between compounds containing aromatic C(sp(2))-H bonds and benzylic ...

Synthesis of (+/-)-vibralactone.

Org. Lett. 10(7) , 1401-4, (2008)

Reductive alkylation of methyl 2-methoxybenzoate with prenyl bromide and hydrolysis afforded methyl 6-oxo-1-prenyl-2-cyclohexenecarboxylate. Reduction of the ketone, hydrolysis, iodolactonization, ozonolysis, and intramolecular aldol reaction provided a spiro...