Methyl 3-bromobenzoate

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Names

[ CAS No. ]:
618-89-3

[ Name ]:
Methyl 3-bromobenzoate

[Synonym ]:
3-methoxycarbonyl-1-bromobenzene
(3-bromophenyl)acetic acid methyl ester
m-bromobenzoic acid methyl ester
Methyl 3-bromobenzoate
Benzoic acid, m-bromo-, methyl ester
MFCD00017777
Benzoic acid,3-bromo-,methyl ester
Methyl-3-brombenzolcarboxylat
Benzoic acid, 3-bromo-, methyl ester
methyl-3-bromobenzoate
Methyl m-bromobenzoate
EINECS 210-569-9
3-MeO2CC6H4Br
3-Bromobenzoic acid,methyl ester

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
244.4±13.0 °C at 760 mmHg

[ Melting Point ]:
31-33 °C(lit.)

[ Molecular Formula ]:
C8H7BrO2

[ Molecular Weight ]:
215.044

[ Flash Point ]:
101.6±19.8 °C

[ Exact Mass ]:
213.962936

[ PSA ]:
26.30000

[ LogP ]:
2.88

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.550

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl benzoate
  • Methanol
  • QVR CE
  • carbon monoxide
  • 1,3-Dibromobenzene
  • 3-Bromobenzaldehyde
  • Methyl 5-bromo-2-iodobenzoate
  • 3-Bromobenzoyl chloride
  • (Diacetoxyiodo)benzene
  • Methyl 3-iodobenzoate

DownStream

  • 3-Phenoxybenzoic acid
  • 3-Bromobenzhydrazide
  • Methyl 3-fluorobenzoate
  • methyl 3-(1-methyl-2-oxo-2-phenylethyl)benzoate
  • Phenyl ethyl ketone
  • Methyl 3'-nitro-[1,1'-biphenyl]-3-carboxylate
  • 3-Methoxycarbonylphenylboronic acid pinacol ester
  • BIPHENYL-3-CARBONYLCHLORIDE
  • 3-(2-PHENYLETHYNYL)BENZOIC ACID ETHYL ESTER
  • 3-PYRROLIDIN-1-YL-BENZOIC ACID METHYL ESTER

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a molecular source of nanoparticles, and the reactions involved in the catalyst-deactivation processes.

Chemistry 18(10) , 2978-86, (2012)

Dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium [(P{(NC(5)H(10))(C(6)H(11))(2)})(2)PdCl(2)] (1) is a highly active and generally applicable C-C cross-coupling catalyst. Apart from its hig...

Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis.

Science 345(6195) , 433-6, (2014)

The routine application of C(sp3)-hybridized nucleophiles in cross-coupling reactions remains an unsolved challenge in organic chemistry. The sluggish transmetalation rates observed for the preferred ...

Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. biaryl formation via cationic pincer-type PdIV intermediates. Gerber R, et al.

Dalton Trans. 40(35) , 8996-9003, (2011)


More Articles

Related Compounds

  • Methyl 4-[(bis{[(2-methyl-2-propanyl)oxy]carbonyl}amino)methyl]-3-bromobenzoate
  • Methyl 3-amino-5-bromobenzoate
  • Methyl 3-(aminomethyl)-5-bromobenzoate hydrochloride
  • Methyl 3-acetyl-5-bromobenzoate
  • methyl 3-(acetoxymethyl)-4-bromobenzoate
  • Methyl 3-amino-2-bromobenzoate
  • 3-Ethoxy-1-(methylamino)butan-2-ol
  • 2-({4-chloro-7H-pyrrolo[2,3-d]pyrimidin-5-yl}methyl)pyrrolidine
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 3-cyclopropyl-3-[(3R)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]butanoic acid
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 3-{[(Tert-butoxy)carbonyl]amino}-1-(3-fluorophenyl)cyclobutane-1-carboxylic acid
  • 6-Methoxy-2-[(prop-2-en-1-yloxy)carbonyl]-1,2,3,4-tetrahydroisoquinoline-4-carboxylic acid