Methyl 3-bromobenzoate
Methyl 3-bromobenzoate structure
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Common Name | Methyl 3-bromobenzoate | ||
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| CAS Number | 618-89-3 | Molecular Weight | 215.044 | |
| Density | 1.5±0.1 g/cm3 | Boiling Point | 244.4±13.0 °C at 760 mmHg | |
| Molecular Formula | C8H7BrO2 | Melting Point | 31-33 °C(lit.) | |
| MSDS | USA | Flash Point | 101.6±19.8 °C | |
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Cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a molecular source of nanoparticles, and the reactions involved in the catalyst-deactivation processes.
Chemistry 18(10) , 2978-86, (2012) Dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium [(P{(NC(5)H(10))(C(6)H(11))(2)})(2)PdCl(2)] (1) is a highly active and generally applicable C-C cross-coupling catalyst. Apart from its high catalytic activity in Suzuki, Heck, and Negishi reactions... |
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Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis.
Science 345(6195) , 433-6, (2014) The routine application of C(sp3)-hybridized nucleophiles in cross-coupling reactions remains an unsolved challenge in organic chemistry. The sluggish transmetalation rates observed for the preferred organoboron reagents in such transformations are a conseque... |
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Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. biaryl formation via cationic pincer-type PdIV intermediates. Gerber R, et al.
Dalton Trans. 40(35) , 8996-9003, (2011)
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