2,2,2-Trifluoroethyltrifluoromethanesulfonate

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Names

[ CAS No. ]:
6226-25-1

[ Name ]:
2,2,2-Trifluoroethyltrifluoromethanesulfonate

[Synonym ]:
2,2,2-Trifluoroethyl trifluoromethanesulphonate
2,2,2-Trifluoroethyl triflate
Methanesulfonic acid, 1,1,1-trifluoro-, 2,2,2-trifluoroethyl ester
EINECS 458-390-7
MFCD00671579
2,2,2-Trifluoroethyl trifluoromethanesulfonate
trifluoromethylsulfonyloxy-2,2,2-trifluoroethane
2,2,2-Trifluoroethyltrifluoromethanesulfonate
Methanesulfonic acid,trifluoro-,2,2,2-trifluoroethyl ester
2,2,2-Trifluoroethyl trifluorometanesulfonic acid
Trifluoromethanesulfonic Acid 2,2,2-Trifluoroethyl Ester
trifluoroethyl triflate
2,2,2-TRIFLUOROETHYLTRIFLATE

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
102.8±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C3H2F6O3S

[ Molecular Weight ]:
232.102

[ Flash Point ]:
16.0±27.3 °C

[ Exact Mass ]:
231.962891

[ PSA ]:
51.75000

[ LogP ]:
2.26

[ Vapour Pressure ]:
38.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.317

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
PB2775000
CHEMICAL NAME :
Methanesulfonic acid, trifluoro-, 2,2,2-trifluoroethyl ester
CAS REGISTRY NUMBER :
6226-25-1
LAST UPDATED :
199806
DATA ITEMS CITED :
3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530474
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
876 ppm/6H
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - other changes Blood - hemorrhage
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530474-2

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H314-H330

[ Precautionary Statements ]:
P260-P280-P284-P301 + P310-P305 + P351 + P338-P310

[ Hazard Codes ]:
Xi: Irritant;T: Toxic;C: Corrosive;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
UN 3265 8 / PGII

[ RTECS ]:
PB2775000

[ HS Code ]:
2905590090

Precursor & DownStream

Precursor

  • 2,2,2-Trifluoroethanol
  • triflic anhydride
  • trifluoromethanesulfonic acid anhydride
  • trifluoromethanesulfonyl bromide
  • trifluoro-ethyl alcohol
  • sodium carbonate
  • TRIFLUOROMETHANESULFONYLCHLORIDE
  • trifluoromethanesulfonyl fluoride
  • Pyridine

DownStream

  • 1-bromo-4-(2,2,2-trifluoroethoxy)benzene
  • 2,2,2-trifluoro-N-(2-phenylethyl)ethanamine
  • 1-phenylmethoxy-4-(2,2,2-trifluoroethoxy)benzene
  • gamma-secretase modulator 2
  • N-(2,2,2-trifluoroethyl)aniline
  • Triphenyl(2,2,2-trifluoroethyl)phosphanium trifluoromethanesulfonate
  • Diethyl 2-acetamido-2-(2,2,2-trifluoroethyl)malonate
  • 4-chloro-5-methoxy-2-(beta,-trifluoro)ethyl-3(2H)-pyridazinone
  • 4-Chloro-5-Methoxy-2-Methylpyridazin-3(2H)-One
  • 1-(2,2,2-trifluoroethyl)piperidin-4-one

Customs

[ HS Code ]: 2905590090

[ Summary ]:
2905590090 other halogenated, sulphonated, nitrated or nitrosated derivatives of acyclic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

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