1-Chloro-4-methoxybenzene

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Names

[ CAS No. ]:
623-12-1

[ Name ]:
1-Chloro-4-methoxybenzene

[Synonym ]:
4-Chloroanisole
MFCD00000616
1-Chloro-4-methoxybenzene
EINECS 210-772-2
p-Anisyl chloride
Benzene, 1-chloro-4-methoxy-
Anisole, p-chloro-
4-Monochloroanisole
4-Chlorophenyl methyl ether
Anisyl chloride
P-CHLOROANISOLE

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
184.4±13.0 °C at 760 mmHg

[ Melting Point ]:
−18 °C(lit.)

[ Molecular Formula ]:
C₇H₇ClO

[ Molecular Weight ]:
142.583

[ Flash Point ]:
78.3±0.0 °C

[ Exact Mass ]:
142.018539

[ PSA ]:
9.23000

[ LogP ]:
2.82

[ Vapour Pressure ]:
1.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.515

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
immiscible

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
UN 2810

[ WGK Germany ]:
3

[ HS Code ]:
29093090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

4-Bromoanisole
4-methoxyphenyl(mesityl)iodonium trifluoromethanesulfonate
Anisole
N,N-Dimethylformamide dimethyl acetal
4-Chlorophenol
4-Iodoanisole
p-Anisidine
p-Anisoyl chloride
1-Triazene,1-(4-methoxyphenyl)-3,3-dimethyl-
1,2-dichloro-tetramethyldisilane

DownStream

1-di(propan-2-yloxy)phosphoryl-4-methoxybenzene
4-Methoxytriphenylamine
Diphenylsulfid
Benzene,1-methoxy-4-(phenylthio)-
Bis(4-methoxyphenyl) sulfide
4-Methoxythiophenol
5-chloro-2-methoxyphenol
Formamide,N-(4-methoxyphenyl)-
2-Bromo-4-chloro-1-methoxybenzene
p-methoxyphenyl disulfide

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Glucose as a clean and renewable reductant in the Pd-nanoparticle-catalyzed reductive homocoupling of bromo- and chloroarenes in water.

J. Org. Chem. 75(11) , 3908-11, (2010)

An efficient and highly sustainable Ullmann-type homocoupling of bromo- and chloroarenes, including the more challenging electron-rich chloroarenes (e.g., 4-chloroanisole), catalyzed by in situ genera...

Single electron transfer mechanism of oxidative dechlorination of 4-chloroanisole on copper (II)-smectite. Govindaraj N, et al.

Environ. Sci. Technol. 21(11) , 1119-23, (1987)

Laser spectroscopic study of the nucleophilic photosubstitution of 4-chloroanisole and 4-fluoroanisole in aqueous solutions. Lemmetyinen H, et al.

J. Photochem. 30(3) , 315-38, (1985)