Ethyl propiolate
Suppliers
Names
[ CAS No. ]:
623-47-2
[ Name ]:
Ethyl propiolate
[Synonym ]:
MFCD00009184
Ethyl 2-propynoate
ethyl prop-2-ynoate
2-Propynoic acid, ethyl ester
EINECS 210-795-8
Ethyl propiolate
Propiolic acid, ethyl ester
Ethylprop-2-inoat
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
120.0±0.0 °C at 760 mmHg
[ Melting Point ]:
9°C
[ Molecular Formula ]:
C5H6O2
[ Molecular Weight ]:
98.100
[ Flash Point ]:
23.3±0.0 °C
[ Exact Mass ]:
98.036781
[ PSA ]:
26.30000
[ LogP ]:
1.42
[ Vapour Pressure ]:
15.5±0.2 mmHg at 25°C
[ Index of Refraction ]:
1.419
[ Storage condition ]:
2-8°C
[ Water Solubility ]:
miscible
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R10;R36/37/38
[ Safety Phrases ]:
S26-S36-S37/39-S16
[ RIDADR ]:
UN 3272 3/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
2916190090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2916190090
[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%
Articles
Food Chem. 183 , 181-9, (2015)
Sauvignon blanc wines are characterised by their varietal aromas and low phenolic content. Mechanical harvesting has been shown to increase several varietal aromas. Likewise, maceration techniques hav...
J. Am. Chem. Soc. 129 , 441, (2007)
The first organocatalytic enantioselective direct alpha-alkynylation of beta-ketoesters and 3-acyl oxindoles is described. It is demonstrated that activated beta-halo-alkynes undergo nucleophilic acet...
J. Org. Chem. 78(3) , 920-34, (2013)
A novel gold-catalyzed method for the regioselective synthesis of highly substituted pyrroles directly from oximes and alkynes was developed via independent optimization of two key steps of the proces...