Hexan-1,6-diol

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Names

[ CAS No. ]:
629-11-8

[ Name ]:
Hexan-1,6-diol

[Synonym ]:
1,6-Hexylene Glycol
6-hydroxy-1-hexanol
EINECS 211-074-0
1,6-Hexanediol solution
1,6-dihydroxyhexane
1,6-hexandiol
Hexamethylenediol
Hexamethylene glycol
1,6-hexadiol
1,6-Hexanediol
hexane-1,6-diol
Hexanediol
MFCD00002985

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
239.7±8.0 °C at 760 mmHg

[ Melting Point ]:
40-43ºC

[ Molecular Formula ]:
C6H14O2

[ Molecular Weight ]:
118.174

[ Flash Point ]:
101.7±0.0 °C

[ Exact Mass ]:
118.099380

[ PSA ]:
40.46000

[ LogP ]:
-0.07

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.450

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
H2O: 0.1 g/mL, clear, colorless | 500 g/L

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MO2100000
CHEMICAL NAME :
1,6-Hexanediol
CAS REGISTRY NUMBER :
629-11-8
BEILSTEIN REFERENCE NO. :
1633461
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C6-H14-O2
MOLECULAR WEIGHT :
118.20
WISWESSER LINE NOTATION :
Q6Q

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,210,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
IHFCAY Industrial Hygiene Foundation of America, Chemical and Toxicological Series, Bulletin. (Pittsburgh, PA) 1947-69. Volume(issue)/page/year: 6,1,1967
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,210,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3730 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1738 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 49,385,1979
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83598 No. of Facilities: 36 (estimated) No. of Industries: 2 No. of Occupations: 6 No. of Employees: 1740 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83598 No. of Facilities: 59 (estimated) No. of Industries: 3 No. of Occupations: 11 No. of Employees: 3529 (estimated) No. of Female Employees: 313 (estimated)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S23-S24/25-S36/37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1

[ RTECS ]:
MO2100000

[ HS Code ]:
2905399090

Synthetic Route

Precursor & DownStream

Precursor

  • UNII:W45XXM0XWE
  • Adipic acid
  • Glutaric acid
  • Succinic acid
  • Dimethyl adipate
  • 2,5-Anhydro-3,4-dideoxyhexitol
  • hexa-2t,4t-dienediamide
  • 6-Hexanolactone
  • UNII:JR71SUM5E9
  • monomethyl adipate

DownStream

  • HEXAMETHYLENE OXIDE
  • 2-METHYLTETRAHYDROPYRAN
  • 2-Ethyltetrahydrofuran
  • 6-[(4-methoxyphenyl)methoxy]hexan-1-ol
  • 6-bromohexanol
  • 1,6-Dibromohexane
  • (((6-BROMOHEXYL)OXY)METHYL)BENZENE
  • 6-Bromohexanoic acid
  • 6-ethoxy-1-hexanol
  • 1,6-Difluorohexane

Customs

[ HS Code ]: 2905399090

[ Summary ]:
2905399090 other diols。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:5.5%。general tariff:30.0%

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Related Compounds

  • 3-Methyl-hexan-1,6-diol
  • 2-Methyl-hexan-1,6-diol
  • 3,4-Diphenyl-hexan-1,6-diol
  • 1,6-Diphenyl-hexan-1,6-diol
  • 2,4,4-Trimethyl-hexan-1,6-diol
  • meso-3,4-Diphenyl-hexan-1,6-diol
  • 1-But-3-ynyl-3,3,5-trimethylpiperidine
  • tetrahydro-3-hydroxy-N-methoxy-N-methyl-3-Thiophenecarboxamide
  • 1-[(1H-Benzimidazole-2-ylimino)methyl]-2-naphthol
  • 2-cyano-N'-[(E)-1H-indol-3-ylmethylidene]acetohydrazide
  • Cyclopropyl L-alaninate hydrochloride
  • {1-[(5-Bromofuran-2-yl)methyl]cyclopropyl}methanamine
  • 5-Bromo-2-(2-methoxyethyl)isoindoline
  • 6-(Ethylmethylamino)-5-methylnicotinic acid hydrochloride
  • N-(4-amino-2-((2-((2,5-dimethoxyphenyl)amino)-2-oxoethyl)thio)-6-oxo-1,6-dihydropyrimidin-5-yl)furan-2-carboxamide
  • 2-((2-oxo-2-phenylethyl)thio)-6-propylpyrimidin-4(3H)-one
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