2-Methoxy-5-nitrophenol

Suppliers

Names

[ CAS No. ]:
636-93-1

[ Name ]:
2-Methoxy-5-nitrophenol

[Synonym ]:
5-nitro-2-methoxyphenol
5-nitroguaiacol
Phenol,2-methoxy-5-nitro
2-Methoxy-5-nitro-phenol
MFCD00015561
2-Methoxy-5-nitrophenol
3-HYDROXY-4-METHOXYNITROBENZENE
2-Methoxy-5-nitrophe
2-Methoxy-5-nitrobenzolol
Phenol, 2-methoxy-5-nitro-
EINECS 211-269-0
2-Hydroxy-4-nitroanisole

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
291.0±0.0 °C at 760 mmHg

[ Melting Point ]:
103-107 °C(lit.)

[ Molecular Formula ]:
C₇H₇NO₄

[ Molecular Weight ]:
169.135

[ Flash Point ]:
147.1±23.7 °C

[ Exact Mass ]:
169.037506

[ PSA ]:
75.28000

[ LogP ]:
1.80

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.583

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn,Xi

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
2811

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
29095090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

3,4-Methylenedioxynitrobenzene
3,4-Dimethoxynitrobenzene
Hexylamine
4-nitrocatechol
Dimethyl sulfate
Guaiacol
Sodium Methylate
Dimethylamine
2-Fluoro-4-nitroanisole
Piperidine

DownStream

3-Hydroxy-4-methoxybenzonitrile
5-chloro-2-methoxyphenol
2-(3-Chloropropoxy)-1-methoxy-4-nitrobenzene
3,4-Dimethoxynitrobenzene
4-Iodo-1,2-dimethoxybenzene
2-cyclopentyloxy-1-methoxy-4-nitrobenzene
3-cyclopentyloxy-4-methoxyaniline
N-(3-hydroxy-4-methoxyphenyl)acetamide
5-Aminoguaiacol
5-iodo-2-methoxyphenol

Customs

[ HS Code ]: 2909500000

[ Summary ]:
2909500000 ether-phenols, ether-alcohol-phenols and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Phase II metabolism in human skin: skin explants show full coverage for glucuronidation, sulfation, N-acetylation, catechol methylation, and glutathione conjugation.

Drug Metab. Dispos. 43(1) , 126-39, (2014)

Although skin is the largest organ of the human body, cutaneous drug metabolism is often overlooked, and existing experimental models are insufficiently validated. This proof-of-concept study investig...

Temperature-dependent regioselectivity of nucleophilic aromatic photosubstitution. Evidence that activation energy controls reactivity.

J. Org. Chem. 78(10) , 4834-9, (2013)

Irradiation (λ > 330 nm) of 2-chloro-4-nitroanisole (1) at 25 °C in aqueous NaOH forms three substitution photoproducts: 2-methoxy-5-nitrophenol (2), 2-chloro-4-nitrophenol (3), and 3-chloro-4-methoxy...

2-METHOXY-5-NITROPHENOL ACETATE
Sodium 2-methoxy-5-nitrophenolate
2-METHOXY-5-NITROPHENOL,SODIUMSALT
4-(1-aminoethyl)-2-methoxy-5-nitrophenol
4-(1-hydroxyethyl)-2-methoxy-5-nitrophenol
2-methoxy-4-(methylamino)-5-nitrophenol
(9H-fluoren-9-yl)methyl N-(3-hydroxypropyl)-N-(2,2,2-trifluoroethyl)carbamate
(9H-fluoren-9-yl)methyl 2-(hydroxymethyl)-3-oxo-1,2,3,4-tetrahydroquinoxaline-1-carboxylate
(9H-fluoren-9-yl)methyl N-[(2-hydroxy-5-methoxyphenyl)methyl]carbamate
(9H-fluoren-9-yl)methyl N-[4-(7-hydroxy-1,2,3,4-tetrahydroisoquinolin-2-yl)-4-oxobutyl]-N-methylcarbamate
(9H-fluoren-9-yl)methyl N-{3-[2-(2-hydroxyethoxy)ethoxy]propyl}carbamate
(9H-fluoren-9-yl)methyl N-[4-(2-hydroxyphenyl)-1,3-thiazol-2-yl]carbamate
(9H-fluoren-9-yl)methyl 6-hydroxy-1,2,3,4-tetrahydroquinoline-1-carboxylate
(9H-fluoren-9-yl)methyl N-(2-hydroxy-4-methylquinolin-6-yl)carbamate
(9H-fluoren-9-yl)methyl 3-hydroxy-3-phenylpyrrolidine-1-carboxylate
9H-fluoren-9-ylmethyl 4-(2-hydroxyethyl)azepane-1-carboxylate

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