tebbe reagent

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Names

[ CAS No. ]:
67719-69-1

[ Name ]:
tebbe reagent

[Synonym ]:
MFCD00151575
tebbe reagent

Chemical & Physical Properties

[ Density]:
0.927

[ Molecular Formula ]:
C13H18AlClTi

[ Molecular Weight ]:
284.58400

[ Flash Point ]:
4ºC

[ Exact Mass ]:
284.03900

[ LogP ]:
4.36090

[ Appearance of Characters ]:
Solution | Dark red to purple

[ Storage condition ]:
Refrigerator

[ Water Solubility ]:
Soluble in toluene, benzene, dichloromethane. Insoluble in water.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H304-H314-H336-H361d-H373

[ Precautionary Statements ]:
P210-P261-P280-P301 + P310-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Highlyflammable;T:Toxic;

[ Risk Phrases ]:
R11;R23/24/25;R34

[ Safety Phrases ]:
S16-S25-S29-S33-S36/37/39

[ RIDADR ]:
UN 2924 3/PG 2

[ WGK Germany ]:
2

[ Packaging Group ]:
II

[ Hazard Class ]:
4.3

[ HS Code ]:
29310099

Articles

Synthesis and in vitro trypanocide activity of several polycyclic drimane-quinone derivatives.

Bioorg. Med. Chem. 11 , 2489-2497, (2003)

The Diels-Alder reaction between two polygodial-derived dienes and simple quinones to yield substituted naphtho- and anthraquinones, is described. The in vitro trypanocide activity for the series was ...

Synthesis of a novel ceramide analogue via Tebbe methylenation and evaluation of its antiproliferative activity.

Org. Lett. 7 , 1645, (2005)

[reaction: see text] A new analogue of (2S,3R)-ceramide (2) with a methylene group at C4 has been synthesized from d-tartaric acid (3) by using Tebbe methylenation as the key step. Compound 2 exhibite...

Synthesis , 165, (1991)


More Articles

Related Compounds

  • Eschenmoser's reagent
  • Comins' Reagent
  • Cornforth reagent
  • Hendrickson's reagent
  • Stang's reagent
  • Freeman's reagent
  • Tert-butyl 4-(aminomethyl)-6,6,6-trifluorohexanoate
  • rac-(2R,3S)-1-[(benzyloxy)carbonyl]-5-oxo-3-phenyl-4-(propan-2-yl)piperazine-2-carboxylic acid
  • rac-tert-butyl 5-amino-2-bromo-1-[(1R,2R)-2-(trifluoromethyl)cyclopropyl]-1H-imidazole-4-carboxylate
  • Tert-butyl 3-amino-4-bromo-5-phenylthiophene-2-carboxylate
  • ethyl (2S)-2-(4-aminobutanamido)-3-(1H-imidazol-4-yl)propanoate
  • 8-[(tert-butoxy)carbonyl]-7H,8H-imidazo[1,2-a]pyrimidine-6-carboxylic acid
  • 8-{[(9H-fluoren-9-yl)methoxy]carbonyl}-7H,8H-imidazo[1,2-a]pyrimidine-6-carboxylic acid
  • Tert-butyl 2-(cyclopentylamino)-1,3-thiazole-4-carboxylate
  • 1-[(Benzyloxy)carbonyl]-8-methyl-1,2,3,4-tetrahydroquinoline-4-carboxylic acid
  • Tert-butyl 2-[(prop-2-en-1-yl)amino]-1,3-thiazole-4-carboxylate
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