2-Chloroethyl ethyl sulfide

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Names

[ CAS No. ]:
693-07-2

[ Name ]:
2-Chloroethyl ethyl sulfide

[Synonym ]:
MFCD00000979
EINECS 211-742-1
1-chloro-2-ethylsulfanylethane

Chemical & Physical Properties

[ Density]:
1.07

[ Boiling Point ]:
156-157 °C

[ Molecular Formula ]:
C4H9ClS

[ Molecular Weight ]:
124.63200

[ Flash Point ]:
52 °C

[ Exact Mass ]:
124.01100

[ PSA ]:
25.30000

[ LogP ]:
1.97830

[ Index of Refraction ]:
1.4875-1.4895

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WQ3250000
CHEMICAL NAME :
Sulfide, chloroethyl ethyl
CAS REGISTRY NUMBER :
693-07-2
BEILSTEIN REFERENCE NO. :
0635672
LAST UPDATED :
199706
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C4-H9-Cl-S
MOLECULAR WEIGHT :
124.64
WISWESSER LINE NOTATION :
G2S2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
252 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
25 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
32 mg/kg/4D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - dehydrogenases Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other transferases

MUTATION DATA

TEST SYSTEM :
Insect - Drosophila melanogaster
DOSE/DURATION :
5 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 13,19,1971

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H301 + H311 + H331-H314-H350

[ Precautionary Statements ]:
P201-P261-P280-P301 + P310-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R10;R22;R36/37/38;R40

[ Safety Phrases ]:
S36/37/39-S26-S16-S45-S27

[ RIDADR ]:
1992

[ RTECS ]:
WQ3250000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-(Ethylsulfanyl)ethanol
  • dichloroethane
  • Ethanethiol
  • 1-ethylsulfanyl-2-butoxy-ethane
  • Sodium ethanethiolate
  • ethene
  • ethyl thiohypochlorite
  • Thionyl chloride
  • 3,6-dithiaoctan-1-ol

DownStream

  • demeton-S-methyl
  • 1-Chloro-2-(ethylsulfinyl)ethane
  • Ethanol,2-(ethylsulfinyl)-
  • 1-ethenylsulfinylethane
  • Thiophene(SIV)
  • Ethanethiol
  • benzene
  • Ethane,1-chloro-2-(ethylsulfonyl)-
  • Ethene, (ethylthio)-(9Cl)
  • thiometon

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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Related Compounds

  • 2-chloroethyl ethyl sulfide
  • 2-chloroethyl-ethyl-[(4-propan-2-ylphenyl)methyl]azanium chloride
  • 2-chloroethyl-ethyl-[2-(3-ethylphenoxy)ethyl]azanium,chloride
  • 2-chloroethyl-ethyl-[2-(2-methoxyphenoxy)ethyl]azanium,chloride
  • 2-chloroethyl-ethyl-[2-(2-propan-2-ylphenoxy)ethyl]azanium,chloride
  • 2-chloroethyl-ethyl-[2-(4-methylphenoxy)ethyl]azanium,chloride