1,2,3,6-Tetrahydropyridine

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Names

[ CAS No. ]:
694-05-3

[ Name ]:
1,2,3,6-Tetrahydropyridine

[Synonym ]:
Pyridine, 1,2,3,6-tetrahydro-
Pyridine, 1,2,3,6-tetrahydro- (8CI)(9CI)
MFCD00005949
T6M CUTJ
EINECS 211-766-2
1,2,3,6-Tetrahydropyridine [UN2410] [Flammable liquid]
1,2,3,6-Tetrahydropyridine

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
110.9±9.0 °C at 760 mmHg

[ Melting Point ]:
−48 °C(lit.)

[ Molecular Formula ]:
C5H9N

[ Molecular Weight ]:
83.132

[ Flash Point ]:
16.1±0.0 °C

[ Exact Mass ]:
83.073502

[ PSA ]:
12.03000

[ LogP ]:
1.05

[ Vapour Pressure ]:
23.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.455

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;Xi: Irritant;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S16-S26-S36/37/39

[ RIDADR ]:
UN 2410 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Pyridinium,1-(phenylmethyl)-, bromide (1:1)
  • 1-benzylpyridinium chloride
  • 1-Benzyl-1,2,3,6-tetrahydropyridine
  • ethyl 3,6-dihydro-2H-pyridine-1-carboxylate
  • 3-Aminopyridine
  • Pyridine
  • Benzyl bromide
  • 1-cyano-1,2,3,6-tetrahydropyridine
  • 1-methyl-5,6-dihydro-2H-pyridine

DownStream

  • 4-(4-Fluorophenyl)piperidine
  • 4-(3-Fluoro-phenyl)-piperidine
  • 4-(2-Fluorophenyl)piperidine
  • Ethanone,1-(3,6-dihydro-1(2H)-pyridinyl)-
  • 1-phenethylpyridin-2-one
  • 4-(4-Chlorophenyl)piperidine
  • 4-(2-chlorophenyl)piperidine
  • 4-(3-Chlorophenyl)piperidine
  • 1-BOC-1,2,3,6-tetrahydropyridine
  • 4-Phenylpiperidine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

The highly-selective 5-HT(1A) agonist F15599 reduces L-DOPA-induced dyskinesia without compromising anti-parkinsonian benefits in the MPTP-lesioned macaque.

Neuropharmacology 97 , 306-11, (2015)

L-3,4-dihydroxyphenylalanine (L-DOPA) is the most effective anti-parkinsonian agent available, but upon chronic administration, patients with Parkinson's disease (PD) experience abnormal involuntary m...

Neuroprotective effects of 5-(4-hydroxy-3-dimethoxybenzylidene)-thiazolidinone in MPTP induced Parkinsonism model in mice.

Neuropharmacology 93 , 209-18, (2015)

Parkinson's disease (PD) is a neurological disorder characterized by degeneration of nigrostriatal dopaminergic (DAergic) system. Present treatment targeting to DAergic system solely ameliorated the s...

A new class of ammonium ylid for [2,3]-sigmatropic rearrangement reactions: ene-endo-spiro ylids.

Org. Lett. 7 , 2075, (2005)

The first examples of sigmatropic rearrangements of ene-endo-spirocyclic, tetrahydropyridine-derived ammonium ylids are reported. Thus, spiro[6.7]-ylids rearrange primarily by a [2,3]-pathway, whereas...


More Articles

Related Compounds

  • 1-BOC-1,2,3,6-tetrahydropyridine
  • Nitroso-1,2,3,6-tetrahydropyridine
  • 1-cyano-1,2,3,6-tetrahydropyridine
  • N-tosyl-1,2,3,6-tetrahydropyridine
  • 6-methyl-1,2,3,6-tetrahydropyridine
  • 2-Phenyl-1,2,3,6-tetrahydropyridine
  • 5-Cyclopropoxy-3-nitropicolinaldehyde
  • 3-Tert-butoxy-5-cyclopropoxypicolinaldehyde
  • 5-Bromo-3-cyclopropoxypicolinaldehyde
  • 3-Cyclopropoxy-2-formylisonicotinamide
  • 3-Cyclopropoxy-2-formylisonicotinic acid
  • 3-Cyclopropoxy-4-fluoropicolinaldehyde
  • 3-Cyclopropoxy-4-iodopicolinaldehyde
  • N-(3-Cyclopropoxy-2-formylpyridin-4-YL)methanesulfonamide
  • 4-Cyclopropoxy-2-formyl-N,N-dimethylnicotinamide
  • 4-Cyclopropoxy-3-nitropicolinaldehyde
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