Glutathione

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Names

[ CAS No. ]:
70-18-8

[ Name ]:
Glutathione

[Synonym ]:
L-Glutathione Reduced
Tathion
L-Norvaline, 5-[[(1R,2Z)-2-[(carboxymethyl)imino]-2-hydroxy-1-(mercaptomethyl)ethyl]imino]-5-hydroxy-, (5Z)-
(5Z)-5-({(1Z,2R)-1-[(Carboxymethyl)imino]-1-hydroxy-3-sulfanyl-2-propanyl}imino)-5-hydroxy-L-norvaline
Deltathione
Glycine, N- (N-L-γ-glutamyl-L-cysteinyl)-
L-γ-Glutamyl-L-cysteinylglycine
Copren
Glycine, L-γ-glutamyl-L-cysteinyl-
Isethion
Glutathione reduced
GSH
Glutathione
Reduced glutathione
(2S)-2-amino-5-[[(2R)-1-(carboxymethylamino)-1-oxo-3-sulfanylpropan-2-yl]amino]-5-oxopentanoic acid
L-γ-Glutamyl-L-cysteiylglycin
Glutathiol
MFCD00065939
EINECS 200-725-4
(2S)-2-Amino-5-({(2R)-1-[(carboxymethyl)amino]-1-oxo-3-sulfanyl-2-propanyl}amino)-5-oxopentanoic acid
Glutathione-SH
N-(N-L-g-Glutamyl-L-cysteinyl)glycine
Glutinal
L-Glutathione
γ-glutamyl-cysteinyl-glycine

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
754.5±60.0 °C at 760 mmHg

[ Melting Point ]:
182-192ºC

[ Molecular Formula ]:
C10H17N3O6S

[ Molecular Weight ]:
307.323

[ Flash Point ]:
410.1±32.9 °C

[ Exact Mass ]:
307.083801

[ PSA ]:
197.62000

[ LogP ]:
-0.87

[ Vapour Pressure ]:
0.0±5.5 mmHg at 25°C

[ Index of Refraction ]:
1.572

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MC0556000
CHEMICAL NAME :
Glycine, N-(N-L-gamma-glutamyl-L-cysteinyl)-
CAS REGISTRY NUMBER :
70-18-8
LAST UPDATED :
199710
DATA ITEMS CITED :
20
MOLECULAR FORMULA :
C10-H17-N3-O6-S
MOLECULAR WEIGHT :
307.36

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4020 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2238 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1250 mg/kg
SEX/DURATION :
female 1-22 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)

MUTATION DATA

TYPE OF TEST :
DNA inhibition
TEST SYSTEM :
Mammal - species unspecified Lymphocyte
DOSE/DURATION :
10 mmol/L
REFERENCE :
CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 31,265,1980 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83371 No. of Facilities: 174 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 1744 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83371 No. of Facilities: 238 (estimated) No. of Industries: 1 No. of Occupations: 7 No. of Employees: 3078 (estimated) No. of Female Employees: 2121 (estimated)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R68

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
MC0556000

[ HS Code ]:
2930909090

Synthetic Route

Precursor & DownStream

Precursor

  • L(-)-Glutathione
  • Boc-Glutathione-OBzl
  • L-γ-glutamyl-S-dimethylphosphinothioyl-L-cysteinylglycine
  • (9-oxo-9,11-dihydro-indolizino[1,2-b]quinolin-7-yl)-butyric acid
  • N-formylglutathione
  • H-L-Cys(Mpt)-Gly-OBut
  • Mpt-L-Cys(Mpt)-Gly-OBut
  • N-(t-butoxycarbonyl)-L-γ-glutamyl-S-dimethylphosphinothioyl-L-cysteinylglycine di-t-butyl ester
  • N-formyl-L-2-amino-4-cyanobutyric acid

DownStream

  • S-(1,2-Dicarboxyethyl)glutathione
  • fumaric acid
  • Ebselen oxide
  • Ascorbic acid
  • L-Theanine
  • o-(2-Benzothiazolyl)phenol
  • S-(2,4-Dinitrophenyl)-Glutathione

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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