4'-Methyl-[1,1'-biphenyl]-2-carboxylic acid

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Names

[ Name ]:
4'-Methyl-[1,1'-biphenyl]-2-carboxylic acid

[Synonym ]:
2-(4-mehtylphenyl)benzoic acid
4'-Methyl-2-biphenylboronic Acid
4'-methyl-biphenyl-2-carboxylic acid
o-Tolylbenzoic acid
4'-Methyl-2-carboxybiphenyl
RARECHEM AL BO 0764
o-(4-methylphenyl)benzoic acid
2-(4-methylphenyl)benzoic acid
[1,1'-Biphenyl]-2-carboxylic acid, 4'-methyl-
2-(P-TOLYL)BENZOIC ACID
4'-methyl-[1,1'-biphenyl]-2-carboxylic acid
4'-Methyl-2-biphenylcarboxylic acid
MFCD00045826
4'-Methylbiphenyl-2-carboxylic acid
EINECS 230-462-0
4-Methyl-2'-biphenylcarboxylic acid

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
354.5±11.0 °C at 760 mmHg

[ Melting Point ]:
146-148°C

[ Molecular Formula ]:
C₁₄H₁₂O₂

[ Molecular Weight ]:
212.244

[ Flash Point ]:
165.3±13.9 °C

[ Exact Mass ]:
212.083725

[ PSA ]:
37.30000

[ LogP ]:
3.46

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.598

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

4'-Methyl-2-cyanobiphenyl
Methyl-4'-methylbiphenyl-2-carboxylat
2-Iodobenzoic acid
4-Tolylboronic acid
2-Bromobenzoic acid
4'-METHYL-[1,1'-BIPHENYL]-2-CARBALDEHYDE
1,2-Benziodoxol-3(1H)-one,1-hydroxy-
Dimethyl (4-methylphenyl)boronate
4,4,5,5-Tetramethyl-2-(p-tolyl)-1,3,2-dioxaborolane
4,4-dimethyl-2-[2-(4-methylphenyl)phenyl]-5H-1,3-oxazole

DownStream

Methyl α-bromo-2-(p-tolyl)benzoate
Methyl-4'-methylbiphenyl-2-carboxylat
tert-Butyl 4'-(bromomethyl)biphenyl-2-carboxylate
tert-Butyl-4'-(methyl)biphenyl-2-carboxylate
2-(4-methylphenyl)aniline
4'-Methyl-2-cyanobiphenyl
4'-METHYL-[1,1'-BIPHENYL]-2-CARBALDEHYDE
4'-(BROMOMETHYL)-[1,1'-BIPHENYL]-2-CARBOXYLIC ACID
2-(4-methylphenyl)benzoyl chloride
2-[4-[[2-but-1-enyl-4-chloro-5-(hydroxymethyl)imidazol-1-yl]methyl]phenyl]benzoic acid

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

4'-Methylbiphenyl-2-carboxylic acid. Narasegowda RS, et al.

Acta Crystallogr. Sect. E Struct. Rep. Online 61(4) , 939-940, (2005)

3'-FLUORO-4'-METHYL-[1,1'-BIPHENYL]-2-CARBOXYLIC ACID
4'-FLUORO-3'-METHYL-[1,1'-BIPHENYL]-2-CARBOXYLIC ACID
4'-[(1,7'-Dimethyl-2'-propyl[2,5'-bi-1H-benzimidazol]-1'-yl)methyl][1,1'-biphenyl]-2-carboxylic Acid
3-METHYL-[1,1'-BIPHENYL]-2-CARBOXYLIC ACID
4-hydroxy-3',4'-dimethoxy-6-methyl-[1,1'-biphenyl]-2-carboxylic acid
4'-[[1,4'-Dimethyl-2'-propyl(2,6'-bi-1H-benzimidazol)-1'-yl]-methyl]-1,1'-biphenyl-2-carboxylic acid 1,1-dimethylethyl ester
4-Chloro-6-[4-fluoro-3-(trifluoromethyl)phenoxy]-5-pyrimidinamine
1-[3-Tert-Butyl-1-(4-Methylphenyl)-1h-Pyrazol-5-Yl]-3-(1,3-Thiazol-2-Yl)urea
(4-{5-[({4-[2-(Benzyloxy)ethyl]-1,3-Thiazol-2-Yl}carbamoyl)amino]-3-Tert-Butyl-1h-Pyrazol-1-Yl}phenyl)acetic Acid
1-[3-Tert-Butyl-1-(4-Methylphenyl)-1h-Pyrazol-5-Yl]-3-{4-[2-(Pyridin-4-Ylmethoxy)ethyl]-1,3-Thiazol-2-Yl}urea
(4-{3-Tert-Butyl-5-[(1,3-Thiazol-2-Ylcarbamoyl)amino]-1h-Pyrazol-1-Yl}phenyl)acetic Acid
Tetramethyl (4-amino-1-hydroxybutane-1,1-diyl)bis(phosphonate)
2-(Bromomethyl)-1-methoxy-4-(propan-2-yl)benzene
trans-1a(2)a(2)-(2,2-Difluoroethyl)-6a(2)-(3-ethoxypropyl)-4-methoxydispiro[cyclohexane-1,2a(2)-[2H]indene-1a(2)(3a(2)H),4a(2)a(2)-imidazolidine]-2a(2)a(2),5a(2)a(2)-dione
N-(Cyclohexylmethyl)-2-[4-(2-pyridinylamino)phenoxy]-3-pyridinecarboxamide
5-Methoxy-2-(pyrimidin-2-yl)pyrimidin-4-ol

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