2-(Bromomethyl)acrylic acid

Suppliers

Names

[ CAS No. ]:
72707-66-5

[ Name ]:
2-(Bromomethyl)acrylic acid

[Synonym ]:
2-Propenoic acid, 2-(bromomethyl)-
2-bromomethylacrilic acid
EINECS 276-774-0
2-(bromomethyl)propenoic acid
2-(Bromomethyl)acrylic acid
MFCD00004259

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
268.8±23.0 °C at 760 mmHg

[ Melting Point ]:
70-73 °C(lit.)

[ Molecular Formula ]:
C4H5BrO2

[ Molecular Weight ]:
164.985

[ Flash Point ]:
116.4±22.6 °C

[ Exact Mass ]:
163.947281

[ PSA ]:
37.30000

[ LogP ]:
1.37

[ Vapour Pressure ]:
0.0±1.2 mmHg at 25°C

[ Index of Refraction ]:
1.517

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2916190090

Synthetic Route

Precursor & DownStream

Precursor

  • Diethyl bis(hydroxymethyl)malonate
  • Methacrylic acid
  • Ethyl 2-(hydroxymethyl)acrylate
  • 3-Bromo-2-(bromomethyl)propanoic acid

DownStream

  • 3-methylidene-5-(2-phenylethenyl)oxolan-2-one
  • 2-(Chloromethyl)acrylic acid ethyl ester
  • Ethyl 2-(bromomethyl)acrylate
  • Tulipalin A
  • 1,5-Hexadiene
  • 2-methylene-5-hexenoic acid
  • 5-hexyl-3-methylideneoxolan-2-one
  • 2(3H)-Furanone,dihydro-3-methylene-5-phenyl-
  • 2(3H)-Furanone,dihydro-3-methylene-5-(phenylmethyl)-
  • 2-(aminomethyl)-3-(4-fluorophenyl)propanoic acid

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Folate analogues. 34. Synthesis and antitumor activity of non-polyglutamylatable inhibitors of dihydrofolate reductase.

J. Med. Chem. 34 , 222, (1991)

Five analogues of methotrextate (MTX), 10-deazaaminopterin (10-DAM), and 10-ethyl-10-deazaaminopterin (10-EDAM) in which the glutamate moiety was replaced by either a gamma-methyleneglutamate or beta-...

Synthesis , 530, (1990)


More Articles


Related Compounds

  • 2-(Bromomethyl)acrylic Acid Ethyl Ester
  • 2-(Bromomethyl)acrylic Acid Methyl Ester
  • 2-bromomethyl-acrylic acid 2,2,3,3,4,4,5,5,6,6,6-undecafluoro-hexyl ester
  • furan-2-acrylic acid azide
  • n-butyl 2-(bromomethyl)prop-2-enoate
  • ethyl-(2Z)-2-(bromomethyl)-3-(4-methoxyphenyl)-propenoate