2-(Bromomethyl)acrylic acid

Modify Date: 2025-08-25 15:28:31

2-(Bromomethyl)acrylic acid Structure
2-(Bromomethyl)acrylic acid structure
Common Name 2-(Bromomethyl)acrylic acid
CAS Number 72707-66-5 Molecular Weight 164.985
Density 1.7±0.1 g/cm3 Boiling Point 268.8±23.0 °C at 760 mmHg
Molecular Formula C4H5BrO2 Melting Point 70-73 °C(lit.)
MSDS Chinese USA Flash Point 116.4±22.6 °C
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 2-(bromomethyl)prop-2-enoic acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.7±0.1 g/cm3
Boiling Point 268.8±23.0 °C at 760 mmHg
Melting Point 70-73 °C(lit.)
Molecular Formula C4H5BrO2
Molecular Weight 164.985
Flash Point 116.4±22.6 °C
Exact Mass 163.947281
PSA 37.30000
LogP 1.37
Vapour Pressure 0.0±1.2 mmHg at 25°C
Index of Refraction 1.517
Storage condition 2-8°C

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C: Corrosive;
Risk Phrases R34
Safety Phrases S26-S36/37/39-S45
RIDADR UN 3261 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 8
HS Code 2916190090

 Synthetic Route

~65%

2-(Bromomethyl)acrylic acid Structure

2-(Bromomethyl)...

CAS#:72707-66-5

Literature: Sun, Chong-Si; Cheng, Hsiu-Yi; Lin, Yu-Shiang; Hou, Duen-Ren Journal of the Chinese Chemical Society, 2008 , vol. 55, # 2 p. 435 - 438

~75%

2-(Bromomethyl)acrylic acid Structure

2-(Bromomethyl)...

CAS#:72707-66-5

Literature: Khazaei, Ardeshir; Vaghei, Ramin Ghorbani; Karkhanei, Ebrahim Synthetic Communications, 2002 , vol. 32, # 14 p. 2107 - 2113

~57%

2-(Bromomethyl)acrylic acid Structure

2-(Bromomethyl)...

CAS#:72707-66-5

Literature: Hoefling, Sarah B.; Hultsch, Christina; Wester, Hans-Juergen; Heinrich, Markus R. Tetrahedron, 2008 , vol. 64, # 52 p. 11846 - 11851

~%

2-(Bromomethyl)acrylic acid Structure

2-(Bromomethyl)...

CAS#:72707-66-5

Literature: Chemische Berichte, , vol. 112, p. 3480 - 3485

 Customs

HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

 Articles2

More Articles
Folate analogues. 34. Synthesis and antitumor activity of non-polyglutamylatable inhibitors of dihydrofolate reductase.

J. Med. Chem. 34 , 222, (1991)

Five analogues of methotrextate (MTX), 10-deazaaminopterin (10-DAM), and 10-ethyl-10-deazaaminopterin (10-EDAM) in which the glutamate moiety was replaced by either a gamma-methyleneglutamate or beta-...

Synthesis , 530, (1990)

 Synonyms

2-Propenoic acid, 2-(bromomethyl)-
2-bromomethylacrilic acid
EINECS 276-774-0
2-(bromomethyl)propenoic acid
2-(Bromomethyl)acrylic acid
MFCD00004259
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