ethyl 2-(trimethylsilylmethyl)prop-2-enoate

Suppliers

Names

[ Name ]:
ethyl 2-(trimethylsilylmethyl)prop-2-enoate

[Synonym ]:
ethyl 2-(trimethylsilylmethyl)acrylate
MFCD00075508
ethyl (2-trimethylsilylmethyl)-prop-2-enoate
(2-Ethoxycarbonylallyl)-trimethylsilane
Ethyl 2-(trimethylsilylmethyl)propenoate
ethyl 2-methylene-3-(trimethylsilyl)propionate
2-(Trimethylsilylmethyl)acrylic acid ethyl ester
ethyl 2-(trimethylsilanylmethyl)acrylate

Chemical & Physical Properties

[ Density]:
0.897 g/mL at 25ºC(lit.)

[ Boiling Point ]:
70-72ºC10 mm Hg(lit.)

[ Molecular Formula ]:
C₉H₁₈O₂Si

[ Molecular Weight ]:
186.32400

[ Flash Point ]:
140 °F

[ Exact Mass ]:
186.10800

[ PSA ]:
26.30000

[ LogP ]:
2.44390

[ Index of Refraction ]:
n20/D 1.438(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
UN 1993

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

ethyl 2-(((methylsulfonyl)oxy)methyl)-3-(trimethylsilyl)propionate
Ethyl 2-hydroxy-2,2-bis[trimethylsilylmethyl]-acetate
Formaldehyde
ethyl 2-diethoxyphosphoryl-3-trimethylsilylpropanoate
bromomethyl-trimethylsilanylmethyl-malonic acid diethyl ester
Propanoic acid,3-(trimethylsilyl)-, ethyl ester
ethyl 2-(hydroxymethyl)-3-(trimethylsilyl)propionate
Ethyl acrylate TOP1 supplier
Chlorotrimethylsilane
(2-(ethoxycarbonyl)allyl)zinc(II) bromide

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Synthesis of Carbohydrate Derived a-Methylene-?-lactones by Diasterecseldctive, Low Temperature Reformatsky-Type Reactions. Csuk R, et al.

J. Carbohydr. Chem. 5(3) , 459-467, (1986)

Synthesis of Carbohydrate Derived α-Methylene-γ-lactones by Diasterecseldctive, Low Temperature Reformatsky-Type Reactions Csuk R, et al.