5-Brom-2-fluorpyridin

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Names

[ CAS No. ]:
766-11-0

[ Name ]:
5-Brom-2-fluorpyridin

[Synonym ]:
5-Bromo-2-fluoropyridine
5-Bromo-2-Fluoro Pyridine
2-Fluoro-5-bromopyridine
3-Bromo-6-fluoropyridine
5-Brom-2-fluorpyridin
Pyridine, 5-bromo-2-fluoro-
MFCD01863742

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
178.0±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H3BrFN

[ Molecular Weight ]:
175.99

[ Flash Point ]:
61.4±21.8 °C

[ Exact Mass ]:
174.943283

[ PSA ]:
12.89000

[ LogP ]:
1.80

[ Vapour Pressure ]:
1.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.534

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37

[ RIDADR ]:
UN 2810

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 6-Fluoronicotinic acid
  • 5-Bromo-2-nitropyridine

DownStream

  • 3-PyridineMethanol, 5-bromo-2-fluoro-α-Methyl-
  • 2-Fluoro-5-pyridylboronic acid
  • 5-Bromo-2-(cyclopropylmethoxy)pyridine
  • 6-Fluoro-3-pyridinol
  • 2-Fluoro-3-formylpyridine
  • 2-Fluoropyridine-5-boronic acid pinacol ester
  • 6-Cyclopropylmethoxypyridine-3-boronic acid pinacol ester
  • (5-Bromo-2-fluoro-3-pyridinyl)boronic acid
  • 5-Bromo-2-(4-piperidinyloxy)pyridine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Versatile synthesis of 3,5-disubstituted 2-fluoropyridines and 2-pyridones.

J. Org. Chem. 68(8) , 3352-5, (2003)

5-bromo-2-fluoro-3-pyridylboronic acid (3) was prepared in high yield by ortho-lithiation of 5-bromo-2-fluoropyridine (1), followed by reaction with trimethylborate. Suzuki reaction of 3 with a range ...

Synthesis of two fluoro analogues of the nicotinic acetylcholine receptor agonist UB-165.

J. Org. Chem. 68(6) , 2475-8, (2003)

Two racemic fluoropyridine analogues 4 and 5 of the potent nicotinic agonist UB-165 have been synthesized. Halogenated pyridines 7 and 12 provided the organometallic reagents needed for the Negishi an...

Aromatic fluorine compounds. XI. Replacement of chlorine by fluorine in halopyridines. Finger GC, et al.

J. Org. Chem. 28(6) , 1666-1668, (1963)


More Articles

Related Compounds

  • 5-Brom-2-methyl-8-nitroisochinolinium-p-toluolsulfonat
  • 5-Brom-2,3-dichlorpyridin
  • 5-Brom-2-(4-brombenzyl)-benzoesaeure
  • 5-Brom-2-propyl-phenol
  • 5-Brom-2-(N-methyl-p-toluolsulfonamido)-benzophenon
  • 5-Brom-2,4-dimethyl-resorcin-diacetat
  • 2-oxo-N-(3-phenylpropyl)-1,2-dihydroquinoline-6-sulfonamide
  • (4-But-3-ynyl-phenyl)-methanol
  • 6-(4-chlorophenyl)-3-(4-methoxyphenyl)-2H-pyrazolo[3,4-b]pyridine-4-carboxylic acid
  • 4-(Benzyl(ethyl)amino)-4-oxobutanoic acid
  • 6-Amino-4-methyl-1-phenylanthrapyridone
  • 3,6-Dimethoxy-2-methylpyridine
  • Methyl 2-chlorosulfonylnaphthalene-1-carboxylate
  • alpha-Methyl-5-hydroxytryptophan ethyl ester
  • 1-Isopropyloxymethyl 1-cyclohexyl carboxylic acid
  • 1-(1-Chlorovinyl)-1-cyclohexyl-carboxylic acid
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