2,6-bis-(Bromomethyl)pyridine

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Names

[ CAS No. ]:
7703-74-4

[ Name ]:
2,6-bis-(Bromomethyl)pyridine

[Synonym ]:
2,6-bis(bromomethyl)pyridine
MFCD00191795

Chemical & Physical Properties

[ Density]:
1.87g/cm3

[ Boiling Point ]:
275.6ºC at 760 mmHg

[ Melting Point ]:
85-87ºC(lit.)

[ Molecular Formula ]:
C7H7Br2N

[ Molecular Weight ]:
264.94500

[ Flash Point ]:
120.5ºC

[ Exact Mass ]:
262.89500

[ PSA ]:
12.89000

[ LogP ]:
2.87140

[ Index of Refraction ]:
1.618

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
22-36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
UN 3335

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Precursor & DownStream

Precursor

  • Pyridine-2,6-dimethanol
  • 2,6-lutidine
  • Dipicolinic acid
  • Diethylpyridin-2,6-dicarboxylat
  • Phenyllithium
  • DiMethyl 2,6-Pyridinedicarboxylate
  • 6-ACETYLPICOLINIC ACID

DownStream

  • 2,6-diformylpyridine
  • 1,4,7,10,13,16(2,6)-hexapyridina-cyclooctadecaphane
  • 3,11-Dithia-17,18-diazatricyclo[11.3.1.15,9]octadeca-1(17),5,7,9(18),13,15-hexaene
  • 3,11,19-trithia[3.3.3]pyridinophane
  • 2,6-Bis((diphenylphosphanyl)methyl)pyridine
  • 2,6-bis(phenoxymethyl)pyridine
  • 2-[[6-[(2-formylphenoxy)methyl]pyridin-2-yl]methoxy]benzaldehyde
  • 3,6,9,12,15,18,21-heptaoxa-27-azabicyclo[21.3.1]heptacosa-1(27),23,25-triene
  • 3,6,9,15-tetrazabicyclo[9.3.1]pentadeca-1(15),11,13-triene

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

A new vanadium (III) complex of 2,6-bis(3,5-diphenylpyrazol-1-ylmethyl)pyridine as a catalyst for ethylene polymerization.

Molecules 18(4) , 4728-38, (2013)

The tridentate ligand 2,6-bis(3,5-diphenylpyrazol-1-ylmethyl)pyridine, abbreviated as 2,6-[(3,5-ph₂pz-CH₂)₂-py], a new pyridine-pyrazole derivative, was prepared from 2,6-bis(bromomethyl)pyridine and ...

Selective palladation of a large (32 ring atom) macrocyclic ligand at a bis(N-heterocyclic carbene) coordination pocket through transmetallation of the corresponding mercury(II) derivative.

Dalton Trans. 41(46) , 14059-67, (2012)

Treatment of N(2),N(6)-bis(6-acrylamidopyridin-2-yl)pyridine-2,6-dicarboxamide with benzimidazole gives the acyclic aza-Michael addition product N(2),N(6)-bis(6-(3-(1H-benzo[d]imidazol-1-yl)propanamid...

Selenoether macrocyclic chemistry-syntheses and ligand properties of new small-ring Se(3)- and Se(2)N-donor macrocycles.

Dalton Trans. (23) , 4569-77, (2009)

Simultaneous dropwise addition of thf/EtOH solutions of Se{(CH(2))(3)OTs}(2) and o-C(6)H(4)(CH(2)SeCN)(2) or NCSe(CH(2))(3)SeCN to a suspension of NaBH(4) in thf/EtOH at room temperature yields gram q...


More Articles


Related Compounds

  • 2,6-bis-(bromomethyl)pyridine hydrobromide
  • 2,6-bis(bromomethyl)pyridine-N-oxide
  • diethyl 2,6-bis(bromomethyl)pyridine-3,5-dicarboxylate
  • 4-Bromo-2,6-bis(bromomethyl)pyridine
  • 4-Iodo-2,6-bis(bromomethyl)pyridine
  • 2,6-bis(bromomethyl)-4-methoxypyridine
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • N-(3-formyl-2-(1-methyl-1H-pyrazol-5-yl)pyridin-4-yl)-2,2-dimethylpropanamide
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 3-(2,6-Difluoro-4-methoxyphenyl)prop-2-en-1-amine
  • 2-(Aminomethyl)-4-(difluoromethyl)-5-(trifluoromethoxy)pyridine-3-carboxamide
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde