2,6-bis-(Bromomethyl)pyridine

Modify Date: 2024-01-02 18:11:12

2,6-bis-(Bromomethyl)pyridine Structure
2,6-bis-(Bromomethyl)pyridine structure
Common Name 2,6-bis-(Bromomethyl)pyridine
CAS Number 7703-74-4 Molecular Weight 264.94500
Density 1.87g/cm3 Boiling Point 275.6ºC at 760 mmHg
Molecular Formula C7H7Br2N Melting Point 85-87ºC(lit.)
MSDS Chinese USA Flash Point 120.5ºC
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2,6-Bis(bromomethyl)pyridine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.87g/cm3
Boiling Point 275.6ºC at 760 mmHg
Melting Point 85-87ºC(lit.)
Molecular Formula C7H7Br2N
Molecular Weight 264.94500
Flash Point 120.5ºC
Exact Mass 262.89500
PSA 12.89000
LogP 2.87140
Index of Refraction 1.618

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn
Risk Phrases 22-36/37/38
Safety Phrases 26-36/37/39
RIDADR UN 3335
WGK Germany 3
HS Code 2933399090

 Synthetic Route

~96%

2,6-bis-(Bromomethyl)pyridine Structure

2,6-bis-(Bromom...

CAS#:7703-74-4

Literature: Xue, Fengtian; Fang, Jianguo; Delker, Silvia L.; Li, Huiying; Martasek, Pavel; Roman, Linda J.; Poulos, Thomas L.; Silverman, Richard B. Journal of Medicinal Chemistry, 2011 , vol. 54, # 7 p. 2039 - 2048

~74%

2,6-bis-(Bromomethyl)pyridine Structure

2,6-bis-(Bromom...

CAS#:7703-74-4

Literature: Liu; Chen; Deng; Tu Synthesis, 2001 , # 14 p. 2078 - 2080

~52%

2,6-bis-(Bromomethyl)pyridine Structure

2,6-bis-(Bromom...

CAS#:7703-74-4

Literature: European Journal of Inorganic Chemistry, , # 12 p. 3284 - 3291

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2,6-bis-(Bromomethyl)pyridine Structure

2,6-bis-(Bromom...

CAS#:7703-74-4

Literature: Journal of the American Chemical Society, , vol. 75, p. 3830

~%

2,6-bis-(Bromomethyl)pyridine Structure

2,6-bis-(Bromom...

CAS#:7703-74-4

Literature: Journal of the American Chemical Society, , vol. 75, p. 3830

~%

2,6-bis-(Bromomethyl)pyridine Structure

2,6-bis-(Bromom...

CAS#:7703-74-4

Literature: Journal of the American Chemical Society, , vol. 75, p. 3830

~%

2,6-bis-(Bromomethyl)pyridine Structure

2,6-bis-(Bromom...

CAS#:7703-74-4

Literature: Journal of the American Chemical Society, , vol. 75, p. 3830

~%

2,6-bis-(Bromomethyl)pyridine Structure

2,6-bis-(Bromom...

CAS#:7703-74-4

Literature: Tetrahedron Letters, , vol. 54, # 43 p. 5771 - 5774

~%

2,6-bis-(Bromomethyl)pyridine Structure

2,6-bis-(Bromom...

CAS#:7703-74-4

Literature: Tetrahedron Letters, , vol. 54, # 43 p. 5771 - 5774

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles5

More Articles
A new vanadium (III) complex of 2,6-bis(3,5-diphenylpyrazol-1-ylmethyl)pyridine as a catalyst for ethylene polymerization.

Molecules 18(4) , 4728-38, (2013)

The tridentate ligand 2,6-bis(3,5-diphenylpyrazol-1-ylmethyl)pyridine, abbreviated as 2,6-[(3,5-ph₂pz-CH₂)₂-py], a new pyridine-pyrazole derivative, was prepared from 2,6-bis(bromomethyl)pyridine and ...

Selective palladation of a large (32 ring atom) macrocyclic ligand at a bis(N-heterocyclic carbene) coordination pocket through transmetallation of the corresponding mercury(II) derivative.

Dalton Trans. 41(46) , 14059-67, (2012)

Treatment of N(2),N(6)-bis(6-acrylamidopyridin-2-yl)pyridine-2,6-dicarboxamide with benzimidazole gives the acyclic aza-Michael addition product N(2),N(6)-bis(6-(3-(1H-benzo[d]imidazol-1-yl)propanamid...

Selenoether macrocyclic chemistry-syntheses and ligand properties of new small-ring Se(3)- and Se(2)N-donor macrocycles.

Dalton Trans. (23) , 4569-77, (2009)

Simultaneous dropwise addition of thf/EtOH solutions of Se{(CH(2))(3)OTs}(2) and o-C(6)H(4)(CH(2)SeCN)(2) or NCSe(CH(2))(3)SeCN to a suspension of NaBH(4) in thf/EtOH at room temperature yields gram q...

 Synonyms

2,6-bis(bromomethyl)pyridine
MFCD00191795