Titanous chloride

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Names

[ CAS No. ]:
7705-07-9

[ Name ]:
Titanous chloride

[Synonym ]:
Titanous chloride
EINECS 231-728-9
MFCD00011266

Chemical & Physical Properties

[ Density]:
1.192 g/mL at 25 °C

[ Boiling Point ]:
100 °C

[ Melting Point ]:
440 °C (dec.)(lit.)

[ Molecular Formula ]:
Cl3Ti

[ Molecular Weight ]:
154.22600

[ Exact Mass ]:
152.85500

[ LogP ]:
2.06850

[ Index of Refraction ]:
1.4856 (25ºC)

[ Stability ]:
Stable, but reacts violently with water and is spontaneously flammable in air.

[ Water Solubility ]:
Soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XR1924000
CHEMICAL NAME :
Titanium chloride
CAS REGISTRY NUMBER :
7705-07-9
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
Cl3-Ti
MOLECULAR WEIGHT :
154.25

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intratesticular
DOSE :
12341 ug/kg
SEX/DURATION :
male 1 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
JRPFA4 Journal of Reproduction and Fertility. (Biochemical Soc. Book Depot, POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK) V.1- 1960- Volume(issue)/page/year: 7,21,1964 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4077 No. of Facilities: 24 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 1314 (estimated) No. of Female Employees: 90 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P222-P231-P280-P305 + P351 + P338-P310-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R35

[ Safety Phrases ]:
S6-S26-S30-S36/37/39-S43-S45

[ RIDADR ]:
UN 3264 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
XR1924000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

Synthetic Route

Precursor & DownStream

Precursor

  • Titanium tetrachloride
  • titanium
  • methylcyclohexane,titanium,toluene
  • Hydrochloric acid
  • Hydrogen
  • DIETHYLALUMINUM CHLORIDE
  • sodium chloride
  • Magnesium
  • Triethylaluminum

DownStream

  • Hydroxylamine
  • nitric oxide
  • nitrogen dioxide
  • nitrous oxide
  • BIADAMANTYLIDENE
  • titanium tetrafluoride
  • Ethyl 2-(1H-indol-2-yl)acetate
  • titanium
  • Titanium tetrachloride
  • Sulfur

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Environ. Sci. Technol. 48(22) , 13181-7, (2014)

The hydrofluoroolefin 2,3,3,3-tetrafluoropropene (HFO-1234yf) has been introduced to replace 1,1,1,2-tetrafluoroethane (HFC-134a) as refrigerant in mobile, including vehicle, air conditioning systems ...

SnCl2/TiCl3-mediated deoximation of oximes in an aqueous solvent.

Molecules 17(3) , 2464-73, (2012)

A simple procedure for SnCl(2)/TiCl(3)-mediated deoximation of ketoximes in an aqueous solvent is reported. Under the conditions developed in this effort, various ketones and aldehydes are produced in...

[Studies on "Fast Green FCF Standard" for the dye standard on the National Institute of Health Sciences].

Eisei Shikenjo Hokoku. (114) , 136-7, (1996)

The raw material for Fast Green FCF was tested for preparation of the "Fast Green FCF Standard (C.I. 42053)". Analytical data obtained were as follows: paper chromatography, only one spot is observed;...


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