(-)-Fenchone

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Names

[ CAS No. ]:
7787-20-4

[ Name ]:
(-)-Fenchone

[Synonym ]:
(1R,4S)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one
EINECS 232-107-5
MFCD00151104
(1R)-(-)-Fenchone
2-Norbornanone, 1,3,3-trimethyl-, (1R,4S)-(+)-
(-)-1,3,3-Trimethyl-2-norbornanone
Bicyclo[2.2.1]heptan-2-one, 1,3,3-trimethyl-, (1R,4S)-
(+)-FENCHONE
(1R,4S)-fenchone

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
193.5±0.0 °C at 760 mmHg

[ Melting Point ]:
5ºC

[ Molecular Formula ]:
C10H16O

[ Molecular Weight ]:
152.233

[ Flash Point ]:
52.8±0.0 °C

[ Exact Mass ]:
152.120117

[ PSA ]:
17.07000

[ LogP ]:
2.13

[ Vapour Pressure ]:
0.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.485

[ Storage condition ]:
Flammables area

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16

[ RIDADR ]:
UN 1224 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
RB7875000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.0

Synthetic Route

Precursor & DownStream

Precursor

  • (+)-Fenchol
  • (1R,4S)-1,3,3-trimethylbicyclo[2.2.1]heptane-2-one oxime
  • Bicyclo[2.2.1]heptane, 2-diazo-1,3,3-trimethyl-, (1R,4S)
  • 3-ethynyl-2,2,4-trimethylbicyclo[2.2.1]heptan-3-ol

DownStream

  • (1S,3R,4R)-2,2,4-trimethyl-3-pyridin-2-ylbicyclo[2.2.1]heptan-3-ol
  • (+)-2-ethyl fenchol
  • (+)-Fenchol
  • (1S,3R,4R)-2,2,4-trimethyl-3-phenylbicyclo[2.2.1]heptan-3-ol

Articles

[Chemical composition of essential oil obtained from Romanian fennel fruits].

Rev. Med. Chir. Soc. Med. Nat. Iasi. 115(2) , 590-4, (2011)

For therapeutical purposes, fennel (Foeniculum vulgare Mill.), an important aromatic plant, is used for its expectorant, antispasmodic, carminative and diuretic properties. The chemical composition, e...

Biosynthesis of monoterpenes: conversion of the acyclic precursors geranyl pyrophosphate and neryl pyrophosphate to the rearranged monoterpenes fenchol and fenchone by a soluble enzyme preparation from fennel (Foeniculum vulgare).

Arch. Biochem. Biophys. 200(2) , 524-33, (1980)

Kinetics and mechanisms of the tropospheric reactions of menthol, borneol, fenchol, camphor, and fenchone with hydroxyl radicals (OH) and chlorine atoms (Cl).

J. Phys. Chem. A 116(16) , 4097-107, (2012)

Relative kinetic techniques have been used to measure the rate coefficients for the reactions of oxygenated terpenes (menthol, borneol, fenchol, camphor, and fenchone) and cyclohexanol with hydroxyl r...


More Articles


Related Compounds

  • (-)-FENCHONE
  • (-)-fenchone oxime
  • fenchone (triphenylphosphoranylidene)hydrazone
  • 1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one
  • (+/-)-fenchone
  • D-FENCHONE
  • 2-Ethyl-4-fluoroaniline;hydrochloride
  • 3-Azidopropane-1-sulfinamide
  • 5-(2-azidoethyl)indane
  • tert-Butyl (2S,3S)-2-(3-bromobenzyl)-3-(2-(dimethylamino)-2-oxoacetamido)pyrrolidine-1-carboxylate
  • 7-bromo-3-(1-methylpiperidin-4-yl)quinazolin-4(3H)-one
  • 5-[4-(Trifluoromethyl)phenoxy]naphthalene-2-carboxylic acid
  • 2-Bromo-6,7-dihydropyrazolo[1,5-a]pyrimidin-5(4H)-one
  • 2-(2,3,4-Trifluorophenyl)prop-2-enoic acid
  • 4-Azido-3-fluoropyridine
  • 2-{[(Tert-butoxy)carbonyl]amino}-5-ethyl-1,3-thiazole-4-carboxylic acid
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