1-(2-(trimethylsilyl)ethoxycarbonyloxy)&

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Names

[ Name ]:
1-(2-(trimethylsilyl)ethoxycarbonyloxy)&

[Synonym ]:
MFCD02683467
1-({[2-(Trimethylsilyl)ethoxy]carbonyl}oxy)-2,5-pyrrolidinedione
(2,5-dioxopyrrolidin-1-yl) 2-trimethylsilylethyl carbonate
2,5-Pyrrolidinedione, 1-[[[2-(trimethylsilyl)ethoxy]carbonyl]oxy]-
1-({[2-(Trimethylsilyl)ethoxy]carbonyl}oxy)pyrrolidine-2,5-dione

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
308.6±44.0 °C at 760 mmHg

[ Melting Point ]:
83-88ºC(lit.)

[ Molecular Formula ]:
C₁₀H₁₇NO₅Si

[ Molecular Weight ]:
259.331

[ Flash Point ]:
140.4±28.4 °C

[ Exact Mass ]:
259.087585

[ PSA ]:
72.91000

[ LogP ]:
0.73

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.479

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

N,N'-Disuccinimidyl carbonate
2-(Trimethylsilyl)ethanol
Triphosgene
N-Hydroxysuccinimide
2-trimethylsilylethyl carbonochloridate

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Synthesis and evaluation of novel activated mixed carbonate reagents for the introduction of the 2-(trimethylsilyl) ethoxycarbonyl (Teoc)-protecting group. Shute RE and Rich DH

Synthesis 1987(04 ) , 346-349, (1987)

1-[2-(Trimethylsilyl)ethoxycarbonyloxy]benzotriazole
1-[2-(trimethylsilyl)ethoxymethyl]imidazole-5-carboxaldehyde
2-Bromo-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-imidazole-4-carbonitrile
1-((2-(trimethylsilyl)ethoxy)methyl)-1H-pyrazolo[3,4-d]pyrimidine-4-carboxylic acid
1-(2-(triMethylsilyl)ethylsulfonyl)-1H-indol-7-amine
(1-((2-(Trimethylsilyl)ethoxy)methyl)-1H-pyrazol-4-yl)boronic acid
2-cyclopentyl-N-(2-((4-(2-fluorophenyl)piperazin-1-yl)sulfonyl)ethyl)acetamide
4-(tert-butyl)-N-(2-((4-(2-fluorophenyl)piperazin-1-yl)sulfonyl)ethyl)benzamide
3,4-difluoro-N-(2-((4-(2-fluorophenyl)piperazin-1-yl)sulfonyl)ethyl)benzamide
N-(2-((4-(2-fluorophenyl)piperazin-1-yl)sulfonyl)ethyl)cinnamamide
2-(4-fluorophenyl)-N-(2-((4-(2-fluorophenyl)piperazin-1-yl)sulfonyl)ethyl)acetamide
N-(2-((4-(2-fluorophenyl)piperazin-1-yl)sulfonyl)ethyl)-4-phenylbutanamide
Ethyl 4-(2-((3-(thiophen-2-yl)-[1,2,4]triazolo[4,3-b]pyridazin-6-yl)thio)acetyl)piperazine-1-carboxylate
N-(5-chloro-2-methoxyphenyl)-2-((3-(thiophen-2-yl)-[1,2,4]triazolo[4,3-b]pyridazin-6-yl)thio)acetamide
N-(2,4-dimethoxyphenyl)-2-((3-(thiophen-2-yl)-[1,2,4]triazolo[4,3-b]pyridazin-6-yl)thio)acetamide
Ethyl 4-(2-((3-(thiophen-2-yl)-[1,2,4]triazolo[4,3-b]pyridazin-6-yl)thio)acetamido)benzoate

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