N-Boc-L-valinol

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Names

[ CAS No. ]:
79069-14-0

[ Name ]:
N-Boc-L-valinol

[Synonym ]:
tert-Butyl [(1S)-1-(hydroxymethyl)-2-methylpropyl]carbamate
Carbamic acid, N-[(1S)-1-(hydroxymethyl)-2-methylpropyl]-, 1,1-dimethylethyl ester
Carbamic acid, N-[(1R)-1-(hydroxymethyl)-2-methylpropyl]-, 1,1-dimethylethyl ester
N-t-BOC-D-Valinol
tert-butyl N-[(2S)-1-hydroxy-3-methylbutan-2-yl]carbamate
tert-Butyl [(2S)-1-hydroxy-3-methylbutan-2-yl]carbamate
tert-Butyl [(2R)-1-hydroxy-3-methylbutan-2-yl]carbamate
2-Methyl-2-propanyl [(2R)-1-hydroxy-3-methyl-2-butanyl]carbamate
2-Methyl-2-propanyl [(2S)-1-hydroxy-3-methyl-2-butanyl]carbamate
MFCD00082635
Boc-Val-ol

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
303.1±25.0 °C at 760 mmHg

[ Molecular Formula ]:
C10H21NO3

[ Molecular Weight ]:
203.279

[ Flash Point ]:
137.1±23.2 °C

[ Exact Mass ]:
203.152145

[ PSA ]:
58.56000

[ LogP ]:
1.71

[ Vapour Pressure ]:
0.0±1.4 mmHg at 25°C

[ Index of Refraction ]:
1.453

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2924199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • boc-val-ome
  • Boc-L-Valine
  • L-Val-ol
  • Di-tert-butyl dicarbonate
  • (4S)-N-tert-butyloxycarbonyl-4-isopropyl-1,3-oxazolidin-5-one
  • tert-Butoxycarbonyl-L-valine N-hydroxysuccinimide ester
  • L-Valine
  • tert-Butyl-4-cyano-4-(dimethyl amino) piperidine-1-carboxylate
  • Di-tert-butyl carbonate

DownStream

  • Cbz-D-beta-homovaline
  • (S)-4-Isopropyl-2-oxazolidinone
  • 2-Oxazolidinone,5-ethynyl-4-(1-methylethyl)-,(4S,5R)-(9CI)
  • (R)-(+)-4-Isopropyl-2-oxazolidinone
  • Boc-D-Valine
  • Fmoc-L-beta-homovaline
  • Boc-D-beta-hoMovaline
  • 4-BOC-(R)-AMINO-5-METHYL HEXANOIC ACID
  • BOC-L-VALINAL
  • TERT-BUTYL [(1R)-1-FORMYL-2-METHYLPROPYL]CARBAMATE

Customs

[ HS Code ]: 2924199090

[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Caputo, R. et al.

Tetrahedron 51 , 12337, (1995)

R. Caputo et al.

Tetrahedron Lett. 36 , 167, (1995)

Tietze, L.F. Burkhardt, O.

Synthesis , 1331, (1994)


More Articles

Related Compounds

  • N-BOC-D/L-VALINOL
  • N-Boc-L-homoserine Methyl Ester 4-Methylbenzenesulfonate
  • N-Boc-L-felinine
  • N-Boc-L-arginine hydrochloride monohydrate
  • N-Boc-L-Pro-L-Pro methyl ester
  • N-Boc-L-lysine
  • 2-(2-iodophenoxy)-N-(2-methoxyethyl)acetamide
  • 3H-Benz[e]indole-2-carboxylic acid, 2-[(5-bromo-2-pyridinyl)amino]-2-oxoethyl ester
  • 3-(2-Pyridin-4-ylquinazolin-4-yl)oxybenzaldehyde
  • [4-(Benzotriazol-1-yl)phenyl]methanol
  • 3-((2-Iodophenoxy)methyl)benzamide
  • 5-Bromo-N-methyl-N-((5-methylisoxazol-3-yl)methyl)nicotinamide
  • N-methyl-N-[(5-methyl-1,2-oxazol-3-yl)methyl]-2-(methylsulfanyl)pyridine-3-carboxamide
  • Imidazo[1,2-a]pyridine-8-carbohydrazide
  • 2-Chloro-6-(prop-2-yn-1-yloxy)benzaldehyde
  • [3-(1H-Imidazol-1-yl)propyl](pentan-3-yl)amine
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