α-​Terpinyl acetate

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Names

[ CAS No. ]:
80-26-2

[ Name ]:
α-​Terpinyl acetate

[Synonym ]:
MFCD00037155
a-terpinyl acetate, (±)
(±)-α-Terpineol acetate
EINECS 201-265-7
2-(4-Methyl-3-cyclohexen-1-yl)-2-propyl acetate
2-(4-Methyl-3-cyclohexen-1-yl)-2-propanyl acetate
p-Menth-1-en-8-ol acetate
3-Cyclohexene-1-methanol, α,α,4-trimethyl-, acetate
(±)-2-(4-Methyl-3-cyclohexen-1-yl)-2-propanylacetat
1-Methyl-1-(4-methylcyclohex-3-en-1-yl)ethyl acetate
L6UTJ A1 DX1&1&OV1
Terpinyl acetate
(±)-a-Terpinyl acetate
p-Menth-1-en-8-ol, acetate

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
239.9±9.0 °C at 760 mmHg

[ Melting Point ]:
220 °C

[ Molecular Formula ]:
C12H20O2

[ Molecular Weight ]:
196.286

[ Flash Point ]:
83.0±17.1 °C

[ Exact Mass ]:
196.146332

[ PSA ]:
26.30000

[ LogP ]:
3.67

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.467

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OT0200000
CHEMICAL NAME :
p-Menth-1-en-8-ol, acetate
CAS REGISTRY NUMBER :
80-26-2
BEILSTEIN REFERENCE NO. :
3198769
LAST UPDATED :
199709
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C12-H20-O2
MOLECULAR WEIGHT :
196.32
WISWESSER LINE NOTATION :
L6UTJ A DXOV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5075 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - somnolence (general depressed activity)
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 58(10),27,1993
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
>1 gm/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 58(10),27,1993 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
130 mg/m3/4H/17W-I
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Liver - fatty liver degeneration Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 58(10),27,1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2063 No. of Facilities: 4671 (estimated) No. of Industries: 24 No. of Occupations: 23 No. of Employees: 44114 (estimated) No. of Female Employees: 28016 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
OT0200000

[ HS Code ]:
2915390090

Precursor & DownStream

Precursor

DownStream

  • Terpinolene
  • alpha-Terpinene
  • (S)-(-)-Limonene
  • Alpha-Terpineol
  • (S)-4-(1-hydroxy-1-methylethyl)-1-cyclohexene-1-methanol
  • (+/-)-5-(1-hydroxy-1-methylethyl)-2-methyl-2-cyclohexen-1-ol 1-monoacetate
  • (4S)-8-acetoxy-p-menth-1-en-7-ol
  • (1R,2R,4S)-8-acetoxy-p-menthane-1,2-diol

Customs

[ HS Code ]: 2915390090

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

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Related Compounds

  • (1R)-alpha-terpinyl acetate
  • (1S)-alpha-terpinyl acetate
  • Terpinolene
  • α-​(chloromethyl)​-​, (αS)​-
  • α-terpinyl ethyl ether
  • α-terpinyl bromide
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