Benzyl 2,2,2-trichloroacetimidate

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Names

[ CAS No. ]:
81927-55-1

[ Name ]:
Benzyl 2,2,2-trichloroacetimidate

[Synonym ]:
Benzyl 2,2,2-trichloroethanimidate
Ethanimidic acid, 2,2,2-trichloro-, phenylmethyl ester
MFCD00000805
Benzyl 2,2,2-trichloroethanimidoate
BENZYL TRICHLOROACETIMIDATE

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
319.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₈Cl₃NO

[ Molecular Weight ]:
252.525

[ Flash Point ]:
107.0±30.1 °C

[ Exact Mass ]:
250.967148

[ PSA ]:
33.08000

[ LogP ]:
3.51

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.550

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2925290090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2925290090

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Tetrahedron Asymmetry 3 , 1547, (1992)

Studies of novel cyclitols. A synthesis of 3'O, 4'O -dimethylfuniculosin. Williams DR, et al.

Tetrahedron Lett. 41(49) , 9397-9401, (2000)

The total synthesis of scytophycin C. Part 1: stereocontrolled synthesis of the C₁? C₃₂ protected seco acid. Paterson I, et al.

Tetrahedron 54(39) , 11935-11954, (1998)

benzyl 2,2,2-trichloroethylimidodicarbonate
benzyl 2-[2-[2-(ethoxycarbonyl)phenyl]-1-ethenyl]benzoate
benzyl 2-(2,2,2-trifluoroacetamido)benzoate
benzyl 2,2,2-trifluoroethyl sulfonate
benzyl 2-[[2-[[2-(tert-butoxycarbonylamino)acetyl]amino]acetyl]amino]acetate
benzyl 2-[[2-[[(2-amino-4-methylpentyl)disulfanyl]methyl]-3-phenylpropanoyl]amino]acetate
2-cyclobutyl-3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methoxypropanamido]propanoic acid
3-[(4-bromo-2-fluorophenyl)carbamoyl]-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoic acid
7-bromo-4-fluoro-5-nitro-2,3-dihydro-1H-indole-2,3-dione
4-(2-Fluoro-4-methylphenyl)pyrrolidine-3-carboxylic acid
5-fluoro-3-iodo-1-methanesulfonyl-1H-indole-2-carboxylic acid
methyl 2-(4-isothiocyanato-1H-pyrazol-1-yl)-2-methylpropanoate
1-(5-Bromo-2-fluorophenyl)-3,3-difluorocyclobutane-1-carboxylic acid
{Dispiro[2.0.4^{4}.1^{3}]nonan-5-yl}methanol
(3-methyl-1-phenyl-1H-pyrazol-4-yl)methyl methanesulfonate
[3-methyl-1-(propan-2-yl)-1H-pyrazol-4-yl]methyl methanesulfonate

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