1-naphthylamine-5-sulfonic acid

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Names

[ CAS No. ]:
84-89-9

[ Name ]:
1-naphthylamine-5-sulfonic acid

[Synonym ]:
1-naphthylamine-5-sulfonic acid
5-Amino-1-naphthalenesulfonic acid
5-Aminonaphthalene-1-sulfonic acid
MFCD00014315
1-Naphthalenesulfonic acid, 5-amino-
EINECS 201-571-0

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Melting Point ]:
>300°C

[ Molecular Formula ]:
C10H9NO3S

[ Molecular Weight ]:
223.248

[ Exact Mass ]:
223.030319

[ PSA ]:
88.77000

[ LogP ]:
0.42

[ Index of Refraction ]:
1.713

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QK1270500
CHEMICAL NAME :
1-Naphthalenesulfonic acid, 5-amino-
CAS REGISTRY NUMBER :
84-89-9
BEILSTEIN REFERENCE NO. :
2214149
LAST UPDATED :
199709
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C10-H9-N-O3-S

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal) Behavioral - muscle weakness
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(1),87,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2880 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal)
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(1),87,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal) Behavioral - muscle weakness
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(1),87,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2990 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal)
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(1),87,1986 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
30 gm/kg/30D-I
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Liver - liver function tests impaired Blood - pigmented or nucleated red blood cells
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(1),87,1986

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H312-H314-H332

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R20/21/22;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2585 8/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
QK1270500

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2921450090

Synthetic Route

Precursor & DownStream

Precursor

  • 1-Aminonaphthalene
  • 1-Naphthalenesulfonicacid, 5-nitro-
  • 5-chloronaphthalene-1-sulfonic acid
  • 2-Naphthalenamine,hydrochloride (1:1)
  • N-(1-Naphthyl)acetamide
  • 1-Naphthalenesulfonic acid
  • Sulfuric acid
  • Chlorosulfonic acid
  • Naphthionic acid

DownStream

  • Martius Yellow
  • Dansyl chloride
  • 5-Amino-1-naphthol-3-sulfonic Acid
  • 5-amino-N,N-dimethylnaphthalene-1-sulfonamide
  • 5-(Dimethylamino)-1-naphthalenesulfonic acid
  • naphthalene-1,2-diamine
  • 5-anilinonaphthalene-1-sulfonic acid
  • 1-Naphthalenol
  • 5-amino-6-hydroxynaphthalene-1-sulfonic acid
  • 1-Aminonaphthalene

Customs

[ HS Code ]: 2921450090

[ Summary ]:
2921450090 1-naphthylamine (α-naphthylamine), 2-naphthylamine (β-naphthylamine) and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

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Related Compounds

  • N-(iodoacetaminoethyl)-1-naphthylamine-5-sulfonic acid
  • guanosine-5'-O-(3-thio-(acetylaminoethyl)-1-naphthylamine-5-sulfonic acid)triphosphate
  • adenosine-5'-triphosphoro-gamma-1-(5-sulfonic acid)naphthyl ethylamidate
  • 1-naphthylamine-8-sulfonic acid
  • 1-chloroisoquinoline-5-sulfonic acid,sulfurous acid
  • 1-Nitroanthraquinone-5-sulfonic acid sodium salt
  • 1-{Bicyclo[2.2.1]hept-5-en-2-yl}-4-oxocyclohexane-1-carboxylic acid
  • 2-[3-(Methoxymethyl)furan-2-yl]-3-methylbutanoic acid
  • 1-[2-(1H-1,3-benzodiazol-2-yl)ethyl]cyclobutane-1-carboxylic acid
  • rac-(1R,2R)-2-(5-bromo-3-fluoro-2-hydroxyphenyl)cyclopropane-1-carboxylic acid
  • Methyl 5-(2-fluoro-1-hydroxyethyl)thiophene-3-carboxylate
  • 2-[1-(3-tert-butyl-1H-pyrazol-4-yl)cyclopropyl]propan-2-amine
  • 3-(Aminomethyl)-3-(5-methoxypyridin-3-yl)cyclobutan-1-ol
  • 2-[3-(Aminomethyl)-2,2-dimethylcyclopropyl]-5-bromophenol
  • 3-[2-Chloro-5-(trifluoromethyl)pyridin-3-yl]butan-1-amine
  • 3-Bromo-2-[(pyrrolidin-3-yl)methyl]phenol
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