Leptomycin B

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Names

[ CAS No. ]:
87081-35-4

[ Name ]:
Leptomycin B

[Synonym ]:
Leptomycin B,(2E,5S,6R,7S,9R,10E,12E,15R,16Z,18E)-19-[(2S,3S)-3,6-Dihydro-3-methyl-6-oxo-2H-pyran-2-yl]-17-ethyl-6-hydroxy-3,5,7,9,11,15-hexamethyl-8-oxo-2,10,12,16,18-nonadecapentaenoicacid
2,10,12,16,18-nonadecapentaenoic acid
2,10,12,16,18-Nonadecapentaenoic acid, 19-[(2S,3S)-3,6-dihydro-3-methyl-6-oxo-2H-pyran-2-yl]-17-ethyl-6-hydroxy-3,5,7,9,11,15-hexamethyl-8-oxo-, (2E,5S,6R,7S,9R,10E,12E,15R,16E,18E)-
2,10,12,16,18-Nonadecapentaenoic acid, 19-[(2S,3S)-3,6-dihydro-3-methyl-6-oxo-2H-pyran-2-yl]-17-ethyl-6-hydroxy-3,5,7,9,11,15-hexamethyl-8-oxo-, (2E,5S,6R,7S,9R,10E,12E,15R,16Z,18E)-
7,9,11,15-hexamethyl-8-oxo--yl)-17-ethyl-6-hydroxy-5
(2E,5S,6R,7S,9R,10E,12E,15R,16E,18E)-17-Ethyl-6-hydroxy-3,5,7,9,11,15-hexamethyl-19-[(2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl]-8-oxo-2,10,12,16,18-nonadecapentaenoic acid
antibioticci940
(2E,5S,6R,7S,9R,10E,12E,15R,16Z,18E)-17-Ethyl-6-hydroxy-3,5,7,9,11,15-hexamethyl-19-[(2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl]-8-oxo-2,10,12,16,18-nonadecapentaenoic acid
antibioticcl1957a
LEPTOMYCIN B FROM STREPTOMYCES SP
Leptomycin B

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
725.8±60.0 °C at 760 mmHg

[ Melting Point ]:
41-44ºC

[ Molecular Formula ]:
C33H48O6

[ Molecular Weight ]:
540.73

[ Flash Point ]:
224.8±26.4 °C

[ Exact Mass ]:
540.345093

[ PSA ]:
100.90000

[ LogP ]:
6.66

[ Vapour Pressure ]:
0.0±5.3 mmHg at 25°C

[ Index of Refraction ]:
1.542

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RA5390000
CHEMICAL NAME :
2,10,12,16,18-Nonadecapentanoic acid, 19-(3,6-dihydro-3-methyl-6-oxo-2H-pyran-2-yl)-17-ethy l- 6-hydroxy-3,5,7,9,11,15-hexamethyl-8-oxo-
CAS REGISTRY NUMBER :
87081-35-4
LAST UPDATED :
199412
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C33-H48-O6
MOLECULAR WEIGHT :
540.81

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3100 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Mutation test systems - not otherwise specified
TEST SYSTEM :
Rodent - mouse Leukocyte
DOSE/DURATION :
1 umol/L
REFERENCE :
PAACA3 Proceedings of the American Association for Cancer Research. (Waverly Press, 428 E. Preston St., Baltimore, MD 21202) V.1- 1954- Volume(issue)/page/year: 26,253,1985

Safety Information

[ Symbol ]:

GHS02, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H301-H311-H331-H370

[ Precautionary Statements ]:
P210-P260-P280-P301 + P310-P311

[ Hazard Codes ]:
T: Toxic;F: Flammable;

[ Risk Phrases ]:
R23/25

[ Safety Phrases ]:
7-16-24-33-45

[ RIDADR ]:
UN 1230 3

[ WGK Germany ]:
3

[ HS Code ]:
2916190090

Synthetic Route

Precursor & DownStream

Precursor

  • (2R,3S)-1-(benzyloxy)-3-methylpent-4-yn-2-ol
  • (S)-4-isopropyl-3-((S,E)-6-(methoxymethoxy)-2,4-dimethylhex-4-enoyl)oxazolidin-2-one
  • (2S,3R,4S,E)-3-((tert-butyldimethylsilyl)oxy)-8-(methoxymethoxy)-2,4,6-trimethyloct-6-enal

DownStream

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

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