TBMP

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Names

[ CAS No. ]:
88-32-4

[ Name ]:
TBMP

[Synonym ]:
2-TERT-BUTYL-4-HYDROXYANISOLE
4-Methoxy-3-te
2-BHA
3-tert-Bha
2-TERT-BUTYLHYDROXYANISOLE
3-tert-butyl-4-methoxy-pheno
2-T-BUTYL-4-HYDROXYANISOLE
3-TERT-BUTYL-4-METHOXYPHENOL
4-Methoxy-3

Chemical & Physical Properties

[ Density]:
1.009 g/cm3

[ Boiling Point ]:
293.3ºC at 760 mmHg

[ Melting Point ]:
64℃

[ Molecular Formula ]:
C₁₁H₁₆O₂

[ Molecular Weight ]:
180.24

[ Flash Point ]:
136ºC

[ Exact Mass ]:
180.11500

[ PSA ]:
29.46000

[ LogP ]:
2.69830

[ Index of Refraction ]:
1.507

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SK1575010

CHEMICAL NAME :: Phenol, 3-tert-butyl-4-methoxy-

CAS REGISTRY NUMBER :: 88-32-4

BEILSTEIN REFERENCE NO. :: 2209222

LAST UPDATED :: 199712

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C11-H16-O2

MOLECULAR WEIGHT :: 180.27

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - hamster

DOSE/DURATION :: 27 gm/kg/3W-C

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors

REFERENCE :: JJIND8 JNCI, Journal of the National Cancer Institute. (Washington, DC) V.61-79, 1978-87. For publisher information, see JNCIEQ. Volume(issue)/page/year: 76,143,1986

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
22-36

[ Safety Phrases ]:
26

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2909500000

[ Summary ]:
2909500000 ether-phenols, ether-alcohol-phenols and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Modulation by dietary factors of BHA-induced alterations in cell kinetics of gastro-intestinal tract tissues in rats.

Food Chem. Toxicol. 29(2) , 79-85, (1991)

To determine the effects of dietary ethanol or fibre on 2(3)-tert-butyl-4-hydroxyanisole (BHA)-induced alterations in cell kinetics in gastro-intestinal tract tissues, groups of six male Wistar rats w...

Antioxidant properties of melatonin: a pulse radiolysis study.

Free Radic. Biol. Med. 26(5-6) , 557-65, (1999)

Various one-electron oxidants such as OH*, tert-BuO*, CCl3OO*, Br2*- and N3*, generated pulse radiolytically in aqueous solutions at pH 7, were scavenged by melatonin to form two main absorption bands...

Chemoprevention of cancer: phenolic antioxidants (BHT, BHA).

Int. J. Biochem. 20(7) , 639-51, (1988)

1. The synthetic phenolic antioxidants (e.g. BHT, BHA) added to human and animal food are able to lengthen the life of organisms and lower the incidence of cancer caused by chemical compounds. 2. On t...