2,5-Di-tert-butylhydroquinone

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Names

[ CAS No. ]:
88-58-4

[ Name ]:
2,5-Di-tert-butylhydroquinone

[Synonym ]:
2,5-Bis(2-methyl-2-propanyl)-1,4-benzenediol
MFCD00008825
2,5-TBHQ
EINECS 201-841-8
1,4-Benzenediol, 2,5-bis(1,1-dimethylethyl)-
2,5-Di-tert-Butyl-1,4-hydroquinone (DBHQ)
2,5-di-tert-butylhydroquinone
2,5-Di-tert-butylbenzene-1,4-diol
2,5-DITERT-BUTYLBENZENE-1,4-DIOL
2,5-Di-tert-butyl-1,4-hydroquinone

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
334.4±37.0 °C at 760 mmHg

[ Melting Point ]:
216-218 °C(lit.)

[ Molecular Formula ]:
C14H22O2

[ Molecular Weight ]:
222.323

[ Flash Point ]:
151.5±21.1 °C

[ Exact Mass ]:
222.161987

[ PSA ]:
40.46000

[ LogP ]:
4.02

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.520

[ Storage condition ]:
Store at RT

[ Stability ]:
Stable. Incompatible with oxidizing agents.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MX5160000
CHEMICAL NAME :
Hydroquinone, 2,5-di-tert-butyl-
CAS REGISTRY NUMBER :
88-58-4
BEILSTEIN REFERENCE NO. :
2049542
LAST UPDATED :
199707
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C14-H22-O2
MOLECULAR WEIGHT :
222.36
WISWESSER LINE NOTATION :
L6V DVJ BX1&1&1 EX1&1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>1800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6426 mg/kg/3W-C
TOXIC EFFECTS :
Blood - change in clotting factors Related to Chronic Data - death
REFERENCE :
JONUAI Journal of Nutrition. (Subscription Dept., 9650 Rockville Pike, Bethesda, MD 20014) V.1- 1928- Volume(issue)/page/year: 109,453,1979 ** TUMORIGENIC DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - hamster
DOSE/DURATION :
134 gm/kg/24W-C
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Gastrointestinal - tumors
REFERENCE :
CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 12,1341,1991 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7949 No. of Facilities: 155 (estimated) No. of Industries: 8 No. of Occupations: 14 No. of Employees: 14136 (estimated) No. of Female Employees: 6832 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
MX5160000

[ HS Code ]:
29072900

Synthetic Route

Precursor & DownStream

Precursor

  • 2,5-Di-tert-butyl-1,4-benzoquinone
  • Hydroquinone
  • Isobutylene
  • tert-Butanol
  • Allyltributyltin
  • 2-Bromo-2-methylpropane
  • Methyl tert-butyl ether
  • 2,5-Di-tert-butyl-4-hydroxy-phenoxyl
  • tert-butyl chloride

DownStream

  • 2,5-DI-TERT-BUTYL-4-HYDROXYANISOLE
  • 1,4-Di-tert-butyl-2,5-dimethoxybenzene
  • Ethyl 4-bromo-1H-indole-2-carboxylate
  • 2,5-Di-tert-butyl-1,4-benzoquinone
  • 4-Hydroxydiphenylamine
  • 2-hydroxy-3,6-di(tert-butyl)-1,4-benzoquinone
  • 2,5-Di-tert-butyl-4-hydroxy-phenoxyl
  • Diphenylamine
  • 1,4-Benzenediol,2,5-bis(1,1-dimethylethyl)-, 1,4-diacetate
  • 1-tert-butyl-2,5-dimethoxy-4-nitrobenzene

Customs

[ HS Code ]: 2907299090

[ Summary ]:
2907299090 polyphenols; phenol-alcohols。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:5.5%。general tariff:30.0%

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Related Compounds

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  • 2,5-di-tert-butyl-thiophene-3-sulfonyl chloride
  • 2,5-Di-tert-butyl-1,3,4-thiadiphosphol
  • 2,5-di(tert-butyl)-2-methyl-1-oxa-2-sila-4-cyclopentene
  • ((2,5-di-tert-butylcyclohexa-2,4-dien-1-yl)methyl)benzene
  • 2,5-Di-tert-butyl-1,2,5-thiadiazolidin-3,4-dion
  • N-[1-(azetidin-3-yl)-1H-pyrazol-5-yl]-2-cyano-2,2-dimethylacetamide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • benzyl N-[2-(4-bromophenyl)-2-hydroxybutyl]carbamate
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine