2-BENZYLOXY-1-METHYLPYRIDINIUM TRIFLUOROMETHANESULFONATE

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Names

[ CAS No. ]:
882980-43-0

[ Name ]:
2-BENZYLOXY-1-METHYLPYRIDINIUM TRIFLUOROMETHANESULFONATE

[Synonym ]:
2-Benzyloxy-1-methylpyridinium triflate,trifluoromethanesulfonate
Dudley Reagent
Bn-OPT
2-Benzyloxy-1-methylpyridinium Trifluoromethanesulfonate

Chemical & Physical Properties

[ Melting Point ]:
85-91ºC

[ Molecular Formula ]:
C14H14F3NO4S

[ Molecular Weight ]:
349.32500

[ Exact Mass ]:
349.06000

[ PSA ]:
78.69000

[ LogP ]:
3.22230

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H315-H318-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
22-37/38-41

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

Articles

Mix-and-heat benzylation of alcohols using a bench-stable pyridinium salt.

J. Org. Chem. 71 , 3923, (2006)

2-Benzyloxy-1-methylpyridinium triflate (1) is a stable, neutral organic salt that converts alcohols into benzyl ethers upon warming. The synthesis and reactivity of 1 are described herein. Benzylatio...

Synthesis of benzyl esters using 2-benzyloxy-1-methylpyridinium triflate.

J. Org. Chem. 72 , 8962, (2007)

Triethylamine (Et3N) mediates esterification reactions between the title reagent (1) and carboxylic acids. Alcohols, phenols, amides, and other sensitive functionality are not affected; a dual role fo...

Dudley, G. B. et al.

Synlett , 3142, (2005)


More Articles

Related Compounds

  • (4-(6-Fluorobenzo[d]thiazol-2-yl)piperazin-1-yl)(pyrazin-2-yl)methanone
  • (4-Methyl-1,2,3-thiadiazol-5-yl)(4-(4-methylbenzo[d]thiazol-2-yl)piperazin-1-yl)methanone
  • 3-Fluoro-4-(4-methoxypiperidin-1-yl)benzoic acid
  • (4-(4-Methylbenzo[d]thiazol-2-yl)piperazin-1-yl)(pyrazin-2-yl)methanone
  • (2,4-Dimethylthiazol-5-yl)(4-(4-methoxybenzo[d]thiazol-2-yl)piperazin-1-yl)methanone
  • (3-methoxy-1-methyl-1H-pyrazol-4-yl)(4-(4-methoxybenzo[d]thiazol-2-yl)piperazin-1-yl)methanone
  • (4-(4-Methoxybenzo[d]thiazol-2-yl)piperazin-1-yl)(pyrazin-2-yl)methanone
  • 2-((1-(3-chlorophenyl)-5-(p-tolyl)-1H-imidazol-2-yl)thio)acetamide
  • [4-(4-Ethoxy-2-benzothiazolyl)-1-piperazinyl]-1H-indol-3-ylmethanone
  • (4-(4-Chlorobenzo[d]thiazol-2-yl)piperazin-1-yl)(2,4-dimethylthiazol-5-yl)methanone
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