4-Chloro-2-nitroaniline

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Names

[ CAS No. ]:
89-63-4

[ Name ]:
4-Chloro-2-nitroaniline

[Synonym ]:
4-chloro-2-nitro-phenylamine
4-chloro-2-nitro-aniline
Red Salt Ciba VI
2-Nitro-4-chloroaniline
Benzenamine,4-chloro-2-nitro
Devol Red Salt F
Red Base Ciba VI
ZR DG BNW
EINECS 201-925-4
1-amino-2-nitro-4-chlorobenzene
MFCD00007836
Benzenamine, 4-chloro-2-nitro-
Aniline,4-chloro-2-nitro
4-Chloro-2-nitroaniline
Red Salt Nbgl
4-Chloro-2-nitrobenzenamine
Devol Red F
Red Base Irga VI
azoamine red 2C

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
308.8±22.0 °C at 760 mmHg

[ Melting Point ]:
117-119 °C(lit.)

[ Molecular Formula ]:
C6H5ClN2O2

[ Molecular Weight ]:
172.569

[ Flash Point ]:
140.5±22.3 °C

[ Exact Mass ]:
172.003952

[ PSA ]:
71.84000

[ LogP ]:
2.74

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.646

[ Water Solubility ]:
INSOLUBLE

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BX1575000
CHEMICAL NAME :
Aniline, 4-chloro-2-nitro-
CAS REGISTRY NUMBER :
89-63-4
BEILSTEIN REFERENCE NO. :
0512436
LAST UPDATED :
199710
DATA ITEMS CITED :
14
MOLECULAR FORMULA :
C6-H5-Cl-N2-O2
MOLECULAR WEIGHT :
172.58
WISWESSER LINE NOTATION :
ZR DG BNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
63 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
3 gm/kg
TOXIC EFFECTS :
Behavioral - general anesthetic

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
20 mg/L
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 10(Suppl 10),1,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X8936 No. of Facilities: 96 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 17827 (estimated) No. of Female Employees: 16443 (estimated)

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300 + H310 + H330-H373-H411

[ Precautionary Statements ]:
P260-P264-P273-P280-P284-P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T+:Verytoxic;N:Dangerous for the environment;

[ Risk Phrases ]:
R26/27/28;R33;R51/53

[ Safety Phrases ]:
S28-S36/37-S45-S61-S28A

[ RIDADR ]:
UN 2237 6.1/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
BX1575000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29214210

Synthetic Route

Precursor & DownStream

Precursor

  • 4-Chloroaniline
  • 3-Nitrochlorobenzene
  • 2-Nitroaniline
  • Benzene,1-azido-2-nitro-
  • N-(4-Chloro-2-nitrophenyl)acetamide
  • 4-Chloro-N-(2-hydroxyethyl)-2-nitroaniline
  • Methanesulfonyl chloride
  • 4-Chloroacetanilide
  • 1,4-Dichloro-2-nitrobenzene
  • Benzene, 1-azido-4-chloro-2-nitro

DownStream

  • 3-chloro-7,9,10-triazabicyclo[4.4.0]deca-2,4,7,9,11-pentaen-8-amine
  • 4-Chlorosalicylic acid
  • 4-Chloro-2-nitrobenzonitrile
  • 6-Chloro-L-tryptophan
  • 6-Chloro-8-quinolinamine
  • 3-chloro-9-oxido-8-oxa-7-aza-9-azoniabicyclo[4.3.0]nona-2,4,6,9-tetraene
  • 4-Chloro-2,6-dinitroaniline
  • 5-(4-chloro-2-nitrophenyl)furan-2-carbaldehyde
  • 1-Bromo-4-chloro-2-nitrobenzene
  • 6-CHLOROQUINOXALINE

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

[Toxicity of 4-chloro-2-nitroaniline and 2-chloro-4-nitroaniline to isolated rat hepatocytes].

Med. Lav. 82(3) , 253-60, (1991)

The toxicity of 4-chloro-2-nitroaniline (4C2NA) and 2-chloro-4-nitroaniline (2C4NA) was investigated on isolated rat hepatocytes following 1-3 hours of exposure to 0.2 and/or 2 mM of these xenobiotics...

Disposition and metabolism of 4-chloro-2-nitroaniline in the male F344 rat.

J. Toxicol. Environ. Health A 12(2-3) , 267-82, (1983)

The disposition and metabolism of 14C-labeled 4-chloro-2-nitroaniline (CNA) was studied in male F344 rats following oral or intravenous (iv) administration. The gastrointestinal absorption of CNA was ...


More Articles


Related Compounds

  • N-butyl-4-chloro-2-nitroaniline
  • N-benzyl-4-chloro-2-nitroaniline
  • N-Isopropyl 4-chloro-2-nitroaniline
  • 4-chloro-2-methoxy-5-nitroaniline
  • 4-Chloro-2-fluoro-6-nitroaniline
  • 4-Chloro-2-fluoro-5-nitroaniline
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 1-(2-Hydroxy-2-methylpropyl)-6-methoxy-1H-indazole-3-carboxylic acid
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide