4-Methoxybenzyl 2,2,2-trichloroethanimidate

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Names

[ Name ]:
4-Methoxybenzyl 2,2,2-trichloroethanimidate

[Synonym ]:
MFCD00134547
4-Methoxybenzyl 2,2,2-trichloroethanimidoate
(4-methoxyphenyl)methyl 2,2,2-trichloroethanimidate
Ethanimidic acid, 2,2,2-trichloro-, (4-methoxyphenyl)methyl ester
4-Methoxybenzyl 2,2,2-trichloroethanimidate

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
348.1±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₁₀Cl₃NO₂

[ Molecular Weight ]:
282.551

[ Flash Point ]:
133.5±30.1 °C

[ Exact Mass ]:
280.977722

[ PSA ]:
42.31000

[ LogP ]:
3.43

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.539

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335-H411

[ Precautionary Statements ]:
P261-P273-P280-P305 + P351 + P338

[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;

[ Risk Phrases ]:
20/21/22-36/37/38-51/53

[ Safety Phrases ]:
26-61

[ RIDADR ]:
UN 3082 9/PG 3

[ HS Code ]:
2925290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Trichloroacetonitrile
4-Methoxybenzyl alcohol

DownStream

methyl (3R)-3-[(4-methoxyphenyl)methoxy]butanoate
4-[(4-methoxyphenyl)methoxy]cyclohexan-1-one
Benzoic acid,4-methoxy-, (4-methoxyphenyl)methyl ester
2,2,2-Trichloroacetamide
(S)-3-(4-methoxybenzyloxy)-2-methylpropionic acid methyl ester
5-[(4-methoxyphenyl)methoxy]pentan-1-ol
3-[(4-methoxyphenyl)methoxy]propanal
4-[(4-methoxyphenyl)methoxy]but-2-en-1-ol
3-(4-Methoxybenzyloxy)-1-propanol
1-methoxy-4-(2-phenylethoxymethyl)benzene

Customs

[ HS Code ]: 2925290090

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Tetrahedron 63 , 3682, (2007)

Tetrahedron Lett. 29 , 4139, (1988)

Tetrahedron Lett. 37 , 1482, (1996)

(4-methoxyphenyl)methyl 2,2,2-trifluoroethanimidate
(4-bromophenyl)methyl 2,2,2-trichloroethanimidate
2-(4-methoxybenzyl)-5-{2-[2-(2-methoxy-ethoxy)-ethoxy]-acetylamino}-2H-pyrazole-3-carboxylic acid
(2R)-4-methoxybenzyl 2-(2-(benzo[d]thiazol-2-yldisulfanyl)-4-oxoazetidin-1-yl)-3-methylbut-3-enoate
N-(4-METHOXYBENZYL)-2-(2-PHENYLACETYL)BENZENECARBOXAMIDE
(3,4-dichlorophenyl)methyl 2,2,2-trichloroethanimidate
(2R,4R)-1-(11BS)-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-2,4-diphenylazetidine
2-(Iodomethyl)morpholin-3-one
5-Chloro-2-cyclobutyl-7-(cyclopropylmethyl)-[1,2,4]triazolo[1,5-a]pyridine
5-Chloro-7-cyclopentyl-2-methyl-[1,2,4]triazolo[1,5-a]pyridine
Tert-butyl 3-(azidomethyl)oxetane-3-carboxylate
5-Chloro-7-cyclobutyl-2-methyl-[1,2,4]triazolo[1,5-a]pyridine
5-Chloro-7-cyclobutyl-2-(pentan-3-yl)-[1,2,4]triazolo[1,5-a]pyridine
(R)-Bis(3,5-di-tert-butylphenyl)(3',4'-dihydro-[1,1'-binaphthalen]-2-yl)phosphine oxide
1-[4-(Diethylamino)phenyl]-1,2,3,4-tetrahydropyrimidine-2,4-dione
5-Chloro-7-cyclobutyl-2-(pentan-2-yl)-[1,2,4]triazolo[1,5-a]pyridine

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