dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii)

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Names

[ CAS No. ]:
905459-27-0

[ Name ]:
dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii)

[Synonym ]:
1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazole,3-chloropyridine,dichloropalladium

Chemical & Physical Properties

[ Melting Point ]:
240℃ (DEC.)

[ Molecular Formula ]:
C32H42Cl3N3Pd

[ Molecular Weight ]:
681.475

[ Exact Mass ]:
679.147888

[ PSA ]:
19.37000

[ LogP ]:
3.80850

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
20/21/22

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
28439000

Articles

A user-friendly, all-purpose Pd-NHC (NHC=N-heterocyclic carbene) precatalyst for the negishi reaction: a step towards a universal cross-coupling catalyst.

Chemistry 12 , 4749, (2006)

We have developed the first user-friendly Negishi protocol capable of routinely cross-coupling all combinations of alkyl and aryl centers. The use of an easily synthesized, air stable, highly active, ...

Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective.

Angew. Chem. Int. Ed. Engl. 46 , 2768, (2007)

Palladium-catalyzed C-C and C-N bond-forming reactions are among the most versatile and powerful synthetic methods. For the last 15 years, N-heterocyclic carbenes (NHCs) have enjoyed increasing popula...

Pd-catalyzed aryl amination mediated by well defined, N-heterocyclic carbene (NHC)-Pd precatalysts, PEPPSI.

Chemistry 14 , 2443, (2008)

Pd-N-heterocyclic carbene (NHC)-catalyzed Buchwald-Hartwig amination protocols mediated by Pd-PEPPSI precatalysts is described. These protocols provide access to a range of hindered and functionalized...


More Articles

Related Compounds

  • N-(4-Aminophenyl)-2-[2-(sec-butyl)phenoxy]-propanamide
  • 1-Allyl-1-pyridin-4-yl-but-3-enylamine dihydrochloride
  • 3-[(3-Chloro-1H-indol-2-ylmethyl)-amino]-propan-1-OL hydrochloride
  • 3-Dimethylaminomethyl-4-propoxy-benzaldehyde hydrochloride
  • 2-Pyrrolidin-2-yl-benzothiazole hemioxalate
  • 2-(2-Isopropyl-imidazol-1-yl)-propionic acid hydrochloride
  • 2-[4-(2-Methyl-piperidine-1-sulfonyl)-phenyl]-ethylamine hydrochloride
  • (4-Methoxy-phenyl)-(2-pyridin-2-YL-ethyl)-amine dihydrochloride
  • 2-(5-Amino-2-benzyl-benzoimidazol-1-yl)-ethanol dihydrochloride
  • 2-(4,5-Dihydro-1H-imidazol-2-ylamino)-4-methylsulfanyl-butyric acid hydrochloride
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