o-tolylmagnesium bromide

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Names

[ CAS No. ]:
932-31-0

[ Name ]:
o-tolylmagnesium bromide

[Synonym ]:
MAGNESIUM,BROMO(2-METHYLPHENYL)-
magnesium,methylbenzene,bromide
EINECS 213-250-2
o-Tolylmagnesium Bromide
2-Methylphenylmagnesium bromide
MFCD00010350
2-TOLYL MAGNESIUM BROMIDE

Chemical & Physical Properties

[ Density]:
1.013 g/mL at 25 °C

[ Boiling Point ]:
110.6ºC at 760mmHg

[ Molecular Formula ]:
C7H7BrMg

[ Molecular Weight ]:
195.33900

[ Flash Point ]:
10ºC

[ Exact Mass ]:
193.95800

[ LogP ]:
2.64080

[ Appearance of Characters ]:
Solution | Gray to brown

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
F+: Highly flammable;C: Corrosive;

[ Risk Phrases ]:
R12

[ Safety Phrases ]:
16-26-33-36/37/39-45

[ RIDADR ]:
UN 3399 4.3/PG 1

[ Packaging Group ]:
II

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Bromotoluene
  • 5-Chloroindoline-2,3-dione

DownStream

  • 1,4-bis(2-methylphenyl)benzene
  • 1-bromo-4-(2-methylphenyl)benzene
  • CYCLOPROPYL 2-METHYLPHENYL KETONE
  • Diphenyl(o-tolyl)phosphine
  • 2-Formylphenylboronic acid
  • Di-o-tolylchlorophosphine
  • n,n-diethyl-o-toluidine
  • 2'-METHYL-2,2,2-TRIFLUOROACETOPHENONE
  • 1-[chloro(phenyl)methyl]-2-methylbenzene

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • O-TOLYLMAGNESIUM CHLORIDE
  • m-tolylmagnesium bromide
  • P-TOLYLMAGNESIUM BROMIDE
  • o-bromophenylmagnesium bromide
  • o-Anisyl bromide
  • o-allylphenylmagnesium bromide
  • 2,5-Dimethoxyphenyl vinyl carbinol
  • tert-Butyl 2-(carbonochloridoyl)-pyrrolidine-1-carboxylate
  • 2-(2-Acetylphenyl)-2-hydroxyacetic acid
  • 5-phenyl-N-(pyridin-2-yl)-1,2-oxazole-3-carboxamide
  • 5-bromo-1-(pyridin-3-ylmethyl)-1H-indole-2,3-dione
  • 2-(benzylsulfanyl)-5-bromo-N-(pyridin-2-yl)pyrimidine-4-carboxamide
  • 2-(benzylsulfanyl)-5-bromo-N-(4-methylpyridin-2-yl)pyrimidine-4-carboxamide
  • 2-oxo-N-[2-(pyrrolidin-1-yl)-2-(thiophen-2-yl)ethyl]-2H-chromene-3-carboxamide
  • 2-chloro-N-[2-(pyrrolidin-1-yl)-2-(thiophen-2-yl)ethyl]benzamide
  • 4-[1-(5-Bromo-2-pyridinyl)-3-pyrrolidinyl]morpholine