1-Bromo-3-(chloromethyl)benzene

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Names

[ CAS No. ]:
932-77-4

[ Name ]:
1-Bromo-3-(chloromethyl)benzene

[Synonym ]:
1-Bromo-3-(chloromethyl)benzene
1-bromo-3-chloromethylbenzene
m-Bromobenzylchloride
3-Bromobenzylchloride
Benzene, 1-bromo-3-(chloromethyl)-
MFCD00040865

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
245.5±15.0 °C at 760 mmHg

[ Melting Point ]:
32.5ºC

[ Molecular Formula ]:
C7H6BrCl

[ Molecular Weight ]:
205.480

[ Flash Point ]:
111.7±10.5 °C

[ Exact Mass ]:
203.934128

[ LogP ]:
3.26

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.570

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2903999090

Synthetic Route

Precursor & DownStream

Precursor

  • 3-Bromobenzyl alcohol
  • 3-Bromotoluene
  • 2-Bromo-p-toluidine
  • Sulfuryl chloride
  • Benzoyl peroxide
  • 1,4-Dioxane
  • Hydrochloric acid
  • 3-(fluoromethyl)phenyl bromide

DownStream

  • diethyl 2-(3-bromobenzyl)Malonate
  • 3-(3-Bromophenyl)propanoic acid
  • 4-(3-Bromophenyl)-2-methylbut-1-ene
  • 3-Bromobenzylamine hydrochloride
  • 4-(3-CYANOPHENYL)-2-METHYL-1-BUTENE
  • 1-bromo-3-(phenoxymethyl)benzene
  • 2-(3-bromo-benzyl)-phenol
  • 1-ALLYL-3-BROMOBENZENE
  • 5-Bromoindanone
  • 3-Bromophenylacetic acid

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Biologically stable [(18)F]-labeled benzylfluoride derivatives.

Nucl. Med. Biol. 27(2) , 163-8, (2000)

Use of the [(18)F]-fluoromethyl phenyl group is an attractive alternative to direct fluorination of phenyl groups because the fluorination of the methyl group takes place under milder reaction conditi...

Bromo Derivatives of Benzylphenols. I. Some Monobromo, Dibromo and Tribromo Derivatives of Ortho and Para Benzylphenols. Huston RC, et al.

J. Am. Chem. Soc. 55(5) , 2146-2149, (1933)

Facile Chlorination of Benzyl Alcohols Using 1, 8-Diazabicyclo [5.4. 0] undec-7-ene (DBU) and Sulfonyl Chlorides. Kim HW, et al.

ChemInform 42(14) , (2011)


More Articles


Related Compounds

  • 1-bromo-3-(chloromethyl)-5-(trifluoromethyl)benzene
  • 1-Bromo-3-(chloromethyl)-5-iodobenzene
  • 1-bromo-3-(chloromethyl)-5-methoxybenzene
  • 1-Bromo-3-(chloromethyl)-2,5-difluorobenzene
  • 1-bromo-3-(chloromethyl)-2-methoxybenzene
  • 1-Bromo-3-(chloromethyl)-5-methylbenzene
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 4-Hydroxy-3,5-diiodobenzenecarbothioamide
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • YC6J39W7DR
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine