1-Bromo-3-(chloromethyl)benzene
Suppliers
Names
[ CAS No. ]:
932-77-4
[ Name ]:
1-Bromo-3-(chloromethyl)benzene
[Synonym ]:
1-Bromo-3-(chloromethyl)benzene
1-bromo-3-chloromethylbenzene
m-Bromobenzylchloride
3-Bromobenzylchloride
Benzene, 1-bromo-3-(chloromethyl)-
MFCD00040865
Chemical & Physical Properties
[ Density]:
1.5±0.1 g/cm3
[ Boiling Point ]:
245.5±15.0 °C at 760 mmHg
[ Melting Point ]:
32.5ºC
[ Molecular Formula ]:
C7H6BrCl
[ Molecular Weight ]:
205.480
[ Flash Point ]:
111.7±10.5 °C
[ Exact Mass ]:
203.934128
[ LogP ]:
3.26
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.570
MSDS
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C:Corrosive;
[ Risk Phrases ]:
R34
[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
8
[ HS Code ]:
2903999090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2903999090
[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Nucl. Med. Biol. 27(2) , 163-8, (2000)
Use of the [(18)F]-fluoromethyl phenyl group is an attractive alternative to direct fluorination of phenyl groups because the fluorination of the methyl group takes place under milder reaction conditi...
Bromo Derivatives of Benzylphenols. I. Some Monobromo, Dibromo and Tribromo Derivatives of Ortho and Para Benzylphenols. Huston RC, et al.J. Am. Chem. Soc. 55(5) , 2146-2149, (1933)
Facile Chlorination of Benzyl Alcohols Using 1, 8-Diazabicyclo [5.4. 0] undec-7-ene (DBU) and Sulfonyl Chlorides. Kim HW, et al.
ChemInform 42(14) , (2011)