1,3-Dichloro-2-propanol

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Names

[ CAS No. ]:
96-23-1

[ Name ]:
1,3-Dichloro-2-propanol

[Synonym ]:
1,3-dichloro-1,3-dideoxyglycerol
2-Propanol, 1,3-dichloro-
glycerol 1,3-dichlorohydrin
U 25,354
1,3-dichloro-2-hydroxypropane
EINECS 202-491-9
1,3-dichlorohydrin
DCP
gdch
1,3-DCP
Enodrin
1,3-di-chloro-2-propanol
1,3-dichloro-2-propyl alcohol
Dichlorohydrin
1,3-dichloropropan-2-ol
MFCD00000951
1,3-Dichloro-2-propanol
Glycerol-α,γ-dichlorohydrin

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
174.3±0.0 °C at 760 mmHg

[ Melting Point ]:
-4 °C

[ Molecular Formula ]:
C3H6Cl2O

[ Molecular Weight ]:
128.985

[ Flash Point ]:
85.6±0.0 °C

[ Exact Mass ]:
127.979568

[ PSA ]:
20.23000

[ LogP ]:
0.66

[ Vapour Pressure ]:
0.4±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.462

[ Water Solubility ]:
soluble. >=10 g/100 mL at 23 ºC

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UB1400000
CHEMICAL NAME :
2-Propanol, 1,3-dichloro-
CAS REGISTRY NUMBER :
96-23-1
BEILSTEIN REFERENCE NO. :
1732063
LAST UPDATED :
199801
DATA ITEMS CITED :
18
MOLECULAR FORMULA :
C3-H6-Cl2-O
MOLECULAR WEIGHT :
128.99
WISWESSER LINE NOTATION :
G1YQ1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
110 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
125 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
25 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
800 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4550 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - tumors

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
DOSE/DURATION :
250 umol/L
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 9,401,1987 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-GERMANY;Carcinogen JAN 1993 OEL-RUSSIA:STEL 5 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5378 No. of Facilities: 3 (estimated) No. of Industries: 1 No. of Occupations: 6 No. of Employees: 200 (estimated) No. of Female Employees: 6 (estimated)

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H312-H350

[ Precautionary Statements ]:
P201-P280-P301 + P310-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R21;R25;R45

[ Safety Phrases ]:
S53-S45-S36/37-S16

[ RIDADR ]:
UN 2750 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
UB1400000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
29055910

Synthetic Route

Precursor & DownStream

Precursor

  • Glycerol
  • Epichlorohydrin
  • ALLYL CHLORIDE
  • 3-Chloro-1,2-propanediol
  • acetic acid
  • Isobutylene
  • 1,3-Dichloroacetone
  • 5'-Chloro-2'-nitro-p-toluanilide
  • Triacetin
  • Butylmagnesium Bromide

DownStream

  • 3-chloro-2-hydroxypropanesulphonic acid
  • thietan-3-ol
  • 1,3-dichloropropene
  • Tristealin
  • 1,3-Dichloroacetone
  • 1,1,3-Trichloroacetone
  • 2-Propanol,1,3-bis(4-methylphenoxy)-
  • (S)-(+)-Epichlorhydrin
  • (R)-(-)-Epichlorohydrin
  • 2-Propanone,1,1-dichloro-

Customs

[ HS Code ]: 2905590090

[ Summary ]:
2905590090 other halogenated, sulphonated, nitrated or nitrosated derivatives of acyclic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

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Related Compounds

  • 1,3-dichloro-2-propanol
  • 1,3-Dichloro-2-propanol-d5
  • 1,3-Dichloro-2-propanol phosphate (3:1)
  • 1,3-Dichloro-2-methyl-2-propanol
  • 1,3-dichloro-2-phenyl-propan-2-ol
  • 1,3-(dichloro)-2-(2,4-difluorophenyl)propan-2-ol
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 3-[(3,4-Dihydro-2H-1-benzopyran-4-yl)amino]propanamide
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • [3,4'-Bipyridin]-2-amine
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine