Methyl bromoacetate

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Names

[ CAS No. ]:
96-32-2

[ Name ]:
Methyl bromoacetate

[Synonym ]:
BROMO METHYLACETATE
METHYL 2-BROMOACETATE
Methyl α-bromoacetate
2-Bromoacetic acid methyl ester
Methyl monobromoacetate
bromoacetic acid methyl ester
EINECS 202-499-2
BAM
Bromoacetic acid methyl
Methyl bromoacetate
MFCD00000189
Acetic acid, 2-bromo-, methyl ester
2-BROMOMETHYL ACETATE
Methyl bomoacetate

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
154.0±0.0 °C at 760 mmHg

[ Melting Point ]:
-50°C

[ Molecular Formula ]:
C3H5BrO2

[ Molecular Weight ]:
152.975

[ Flash Point ]:
62.8±0.0 °C

[ Exact Mass ]:
151.947281

[ PSA ]:
26.30000

[ LogP ]:
0.84

[ Vapour Pressure ]:
3.2±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.450

[ Freezing Point ]:
<-50℃

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AF6300000
CHEMICAL NAME :
Acetic acid, bromo-, methyl ester
CAS REGISTRY NUMBER :
96-32-2
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C3-H5-Br-O2
MOLECULAR WEIGHT :
152.99
WISWESSER LINE NOTATION :
E1VO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
15800 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,138,1954 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7133 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1822 (estimated) No. of Female Employees: 272 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H314-H335

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
S26-S36/37/39-S45-S28A-S36-S16

[ RIDADR ]:
UN 2643 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
AF6300000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
29159080

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • Bromoacetyl bromide
  • Bromoacetic acid
  • Dimethyl sulfate
  • carbon monoxide
  • Dibromomethane
  • dimethoxymethane
  • Methyl acetate
  • diazomethane

DownStream

  • ethyl 2-(3-methyl-1,2-dihydroimidazol-1-ium-1-yl)acetate,bromide
  • 2-(Triphenylphosphoranylidene)butanedioic acid dimethyl ester
  • Methyl(E)-3-(2-chlorophenyl)acrylate
  • methyl 3-(2-chlorophenyl)prop-2-enoate
  • dibutyl-(2-methoxy-2-oxoethyl)tellanium,bromide
  • methyl (E)-3-morpholin-4-ylprop-2-enoate
  • 2-(Bromoacetyl)-1,3-benzothiazole
  • METHYL 3-METHOXYACRYLATE
  • Methyl 4-methoxyacetoacetate
  • 3,4-dihydroquinoxalin-2-ol

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Studies on the collision-induced dissociation of adipoR agonists after electrospray ionization and their implementation in sports drug testing.

J. Mass Spectrom. 50(2) , 407-17, (2015)

AdipoR agonists are small, orally active molecules capable of mimicking the protein adiponectin, which represents an adipokine with antidiabetic and antiatherogenic effects. Two adiponectin receptors ...

Synthesis and characterization of some new 4-hydroxy-coumarin derivatives.

Molecules 19(8) , 11791-9, (2014)

Some novel coumarins were synthesized starting from 4-hydroxycoumarin and methyl bromoacetate. The structures of the newly obtained compounds were confirmed by elemental analysis, mass, IR and NMR spe...

One-pot method for stereoselective cyclopropanation of electron-deficient olefins with methyl bromoacetate and phenacyl bromide in the presence of triphenylarsine. Ren Z, et al.

Synthesis 2005(16) , 2718-22, (2005)


More Articles

Related Compounds

  • Methyl bromoacetate-2,2-d2
  • methyl bromoacetate, [2-14c]
  • (4-methoxyphenyl)methyl bromoacetate
  • (E)-<3'-(3''-methoxypropyl)-3',5',5'-trimethyl-2'-oxocyclopentylidene>methyl bromoacetate
  • methyl 2-benzamido-2-bromoacetate
  • methyl 2-(benzylthio)-2-bromoacetate