Nitroxylol

Names

[ CAS No. ]:
99-12-7

[ Name ]:
Nitroxylol

[Synonym ]:
MFCD00007269
1,3-dimethyl-5-nitrobenzene
EINECS 202-732-8

Chemical & Physical Properties

[ Density]:
1.129 g/cm3

[ Boiling Point ]:
273 °C739 mm Hg(lit.)

[ Melting Point ]:
72-74 °C(lit.)

[ Molecular Formula ]:
C₈H₉NO₂

[ Molecular Weight ]:
151.16300

[ Flash Point ]:
273°C

[ Exact Mass ]:
151.06300

[ PSA ]:
45.82000

[ LogP ]:
2.73480

[ Index of Refraction ]:
1.547

MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H373

[ Precautionary Statements ]:
P261-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R23/24/25;R33

[ Safety Phrases ]:
S45-S36/37

[ RIDADR ]:
UN 3447 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2904209090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-Bromo-3,5-dimethylbenzene
3,5-Dimethylphenylboronic acid
3,5-Dimethylaniline
m-Xylene
2,4-Dimethyl-6-nitroaniline
1-Iodo-3,5-dimethylbenzene
2',4'-Acetoxylidine
Tetrabutylammonium cyanide
Acetamide,N-(2,4-dimethyl-6-nitrophenyl)-

DownStream

N,N,3,5-Tetramethylaniline
4-Bromo-3,5-dimethylaniline
5,7-dimethylquinoline
5-bromo-2-(4-bromo-2,6-dimethylphenyl)-1,3-dimethylbenzene
5-Nitroisophthalic acid
3-Methyl-5-nitrobenzoic acid
3-Hydroxy-5-Methylbenzoic Acid
2,5,7-Trimethylquinoline
3,5-Dimethylaniline
2-Nitro-isophthalic acid

Customs

[ HS Code ]: 2904209090

[ Summary ]:
2904209090 derivatives containing only nitro or only nitroso groups。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Preparation of symmetric and asymmetric aromatic azo compounds from aromatic amines or nitro compounds using supported gold catalysts.

Nat. Protoc. 5(3) , 429-38, (2010)

This protocol describes the aerobic oxidation of aromatic anilines to aromatic azo compounds using gold (Au) nanoparticles supported on TiO(2) as a catalyst. Yields above 98% are achieved under a few ...

Nitroxylol
Nitroxylol