Journal of Organic Chemistry 2012-08-03

Tandem ring-opening decarboxylation of cyclopropane hemimalonates with sodium azide: a short route to γ-aminobutyric acid esters.

Michael R Emmett, Huck K Grover, Michael A Kerr

文献索引：J. Org. Chem. 77(15) , 6634-7, (2012)

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摘要

Cyclopropane hemimalonates, when treated with sodium azide, undergo a tandem ring-opening decarboxylation to produce γ-azidobutyric acids in good yields. These adducts were hydrogenated to form γ-aminobutyric acid (GABA) methyl esters.

相关化合物

  • 叠氮化钠
  • 4-氨基丁酸甲酯盐酸...

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