Journal of Organic Chemistry 2012-02-17

Selective palladium-catalyzed C-F activation/carbon-carbon bond formation of polyfluoroaryl oxazolines.

Daohong Yu, Qilong Shen, Long Lu

文献索引：J. Org. Chem. 4th ed., 77 , 1798-1804, (2012)

摘要

A selective palladium-catalyzed Suzuki-Miyaura coupling reaction of polyfluorophenyl oxazolines through ortho C-F activation is described. It was found that reactions with DPPF as the ligand occurred much faster than those with other ligands. A variety of arylboronic acids including challenging functionalized arylboronic acids such as enolizable ketones, aldehyde, cyano, ester, and trifluoromethyl groups were tolerated with the reaction conditions.

相关文献：

ipso-Nitration of arylboronic acids with bismuth nitrate and perdisulfate.

2012-04-06

[Org. Lett. 7th ed., 14 , 1736-1739, (2012)]

Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones.

2012-05-07

[Chem. Commun. (Camb.) 36th ed., 48 , 4332-4334, (2012)]

Pt nanoparticles@photoactive metal-organic frameworks: efficient hydrogen evolution via synergistic photoexcitation and electron injection.

2012-05-02

[J. Am. Chem. Soc. 17th ed., 134 , 7211-7214, (2012)]

Copper-mediated aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides at room temperature.

2012-04-18

[J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012)]

Ambient temperature synthesis of high enantiopurity N-protected peptidyl ketones by peptidyl thiol ester-boronic acid cross-coupling.

2007-02-07

[J. Am. Chem. Soc. 129 , 1132, (2007)]

Selective palladium-catalyzed C-F activation/carbon-carbon bond formation of polyfluoroaryl oxazolines.

摘要

相关化合物

相关文献：

更多文献...