4-甲酯基苯硼酸
4-甲酯基苯硼酸结构式
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常用名 | 4-甲酯基苯硼酸 | 英文名 | Methyl 4-boronobenzoate |
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| CAS号 | 99768-12-4 | 分子量 | 179.97 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 345.8±44.0 °C at 760 mmHg | |
| 分子式 | C8H9BO4 | 熔点 | 197-200 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 162.9±28.4 °C |
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ipso-Nitration of arylboronic acids with bismuth nitrate and perdisulfate.
Org. Lett. 7th ed., 14 , 1736-1739, (2012) An efficient and one pot synthetic method of ipso-nitration of arylboronic acids has been developed. The high efficiency, general applicability, and broader substrate scope including heterocycles and functional groups make this method advantageous. Due to its... |
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Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones.
Chem. Commun. (Camb.) 36th ed., 48 , 4332-4334, (2012) A novel catalytic method for synthesizing 4-aryl-2-quinolinones is reported. The process involves two mechanistically independent, sequential Pd(II)-catalyzed reactions--the oxidative Heck reaction and the intramolecular C-H amidation--both of which smoothly ... |
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Pt nanoparticles@photoactive metal-organic frameworks: efficient hydrogen evolution via synergistic photoexcitation and electron injection.
J. Am. Chem. Soc. 17th ed., 134 , 7211-7214, (2012) Pt nanoparticles of 2-3 nm and 5-6 nm in diameter were loaded into stable, porous, and phosphorescent metal-organic frameworks (MOFs 1 and 2) built from [Ir(ppy)(2)(bpy)](+)-derived dicarboxylate ligands (L(1) and L(2)) and Zr(6)(μ(3)-O)(4)(μ(3)-OH)(4)(carbox... |
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Copper-mediated aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides at room temperature.
J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012) A Cu-mediated ligandless aerobic fluoroalkylation of arylboronic acids under mild conditions is described for the first time. The reaction tolerates a wide range of functional groups, allowing for further transformation. Mechanistic studies suggest that [R(f)... |
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Selective palladium-catalyzed C-F activation/carbon-carbon bond formation of polyfluoroaryl oxazolines.
J. Org. Chem. 4th ed., 77 , 1798-1804, (2012) A selective palladium-catalyzed Suzuki-Miyaura coupling reaction of polyfluorophenyl oxazolines through ortho C-F activation is described. It was found that reactions with DPPF as the ligand occurred much faster than those with other ligands. A variety of ary... |
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Ambient temperature synthesis of high enantiopurity N-protected peptidyl ketones by peptidyl thiol ester-boronic acid cross-coupling.
J. Am. Chem. Soc. 129 , 1132, (2007) alpha-Amino acid thiol esters derived from N-protected mono-, di-, and tripeptides couple with aryl, pi-electron-rich heteroaryl, or alkenyl boronic acids in the presence of stoichiometric Cu(I) thiophene-2-carboxylate and catalytic Pd(2)(dba)(3)/triethylphos... |
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Copper-catalyzed nitration of arylboronic acids with nitrite salts under mild conditions: an efficient synthesis of nitroaromatics Yan, G.; Zhang, L.; Yu, J.
Lett. Org. Chem. 2nd ed., 9 , 133-137, (2012)
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A Highly Practical and Reliable Nickel Catalyst for Suzuki-Miyaura Coupling of Aryl Halides Zhao, Y-L.; et al.
Adv. Synth. Catal. 16th ed., 353 , 2881, (2011)
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Chromenones as potent bradykinin B1 antagonists Bryan, M. C.; et al.
Bioorg. Med. Chem. 1st ed., 22 , 619-622, (2012)
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Synthesis and biological evaluation of salicylate-based compounds as a novel class of methionine aminopeptidase inhibitors Wang, W-L.; Chai, S. C.; Ye, Q-Z.
Bioorg. Med. Chem. 23th ed., 21 , 7151-7154, (2011)
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